C₂₆H₃₉NO₂SSi

Base Information

• Chemical Name: C₂₆H₃₉NO₂SSi
• CAS No.: 898237-80-4
• Molecular Formula: C₂₆H₃₉NO₂SSi
• Molecular Weight: 457.753
• Mol file: 898237-80-4.mol

Synonyms:C₂₆H₃₉NO₂SSi

Chemical Property of C₂₆H₃₉NO₂SSi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₆H₃₉NO₂SSi

There total 1 articles about C₂₆H₃₉NO₂SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

tert-butyldimethylsilyl chloride (18162-48-6) + (-)-(Z)-(1R,2R)-2-isopropyl-4-[(S)-N-methyl-S-phenylsulfonimidoyl]-1-phenylbut-3-en-1-ol (172748-23-1) → C26H39NO2SSi (898237-80-4)

Guidance literature:

With 1H-imidazole; In dichloromethane; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1002/chem.200800455

Reference yield: 93.0%

C26H39NO2SSi (898237-80-4) → C26H39NO2SSi (1058213-68-5)

Guidance literature:

With n-butyllithium; In diethyl ether; hexane; at -40 - 20 ℃; Inert atmosphere;

DOI:10.1002/chem.200800455

Reference yield: 71.0%

C26H39NO2SSi (898237-80-4) + methyllithium (917-54-4) → tert-butyl ((1R,2R,E)-2-isopropyl-1-phenylpent-3-enyloxy)dimethylsilane (1058214-02-0) + tert-butyl [(1R,2R)-2-isopropyl-4-methyl-1-phenylpent-3-enyloxy]dimethylsilane (1058214-00-8)

Guidance literature:

C₂₆H₃₉NO₂SSi; methyllithium; With copper(l) iodide; In diethyl ether; at -40 - 20 ℃; Inert atmosphere;

With water; ammonium chloride; In diethyl ether; at 20 ℃; Inert atmosphere;

DOI:10.1002/chem.200800455

upstream raw materials:

tert-butyldimethylsilyl chloride

(-)-(Z)-(1R,2R)-2-isopropyl-4-[(S)-N-methyl-S-phenylsulfonimidoyl]-1-phenylbut-3-en-1-ol

Downstream raw materials:

C₂₆H₃₉NO₂SSi

tert-butyl [(1R,2R)-2-isopropyl-4-methyl-1-phenylpent-3-enyloxy]dimethylsilane

C₂₀H₃₃⁽²⁾HOSi

tert-butyl ((1R,2R,E)-2-isopropyl-1-phenylpent-3-enyloxy)dimethylsilane