12-benzyloxydodecyl tosylate

Base Information

• Chemical Name: 12-benzyloxydodecyl tosylate
• CAS No.: 1026021-85-1
• Molecular Formula: C₂₆H₃₈O₄S
• Molecular Weight: 446.651
• Mol file: 1026021-85-1.mol

Synonyms:12-benzyloxydodecyl tosylate

Chemical Property of 12-benzyloxydodecyl tosylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 12-benzyloxydodecyl tosylate

There total 3 articles about 12-benzyloxydodecyl tosylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

12-(benzyloxy)dodecan-1-ol (134834-32-5) + p-toluenesulfonyl chloride (98-59-9) → 12-benzyloxydodecyl tosylate (1026021-85-1)

Guidance literature:

With pyridine; at 0 - 5 ℃;

DOI:10.1016/j.tet.2008.02.040

Reference yield:

1,12-dodecandiol (5675-51-4) → 12-benzyloxydodecyl tosylate (1026021-85-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 48 percent / NaH / tetrahydrofuran / 2 h / Heating

2: pyridine / CH₂Cl₂ / 72 h / 20 °C

With pyridine; sodium hydride; In tetrahydrofuran; dichloromethane;

DOI:10.1016/S0040-4020(00)00904-2

Reference yield:

benzyl bromide (100-39-0) → 12-benzyloxydodecyl tosylate (1026021-85-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 48 percent / NaH / tetrahydrofuran / 2 h / Heating

2: pyridine / CH₂Cl₂ / 72 h / 20 °C

With pyridine; sodium hydride; In tetrahydrofuran; dichloromethane;

DOI:10.1016/S0040-4020(00)00904-2

upstream raw materials:

12-(benzyloxy)dodecan-1-ol

p-toluenesulfonyl chloride

1,12-dodecandiol

benzyl bromide

Downstream raw materials:

dl-4-(13-benzyloxy)tridecyl-1,3-dioxolan-2-one

dl-15-benzyloxy-1,2-pentadecandiol

((pentadec-14-en-1-yloxy)methyl)benzene

12-iodododecanol benzyl ether