(2R,4R)-2-methyl-4-<<(4-methylphenyl)sulfonyl>oxy>-6-(phenylthio)-1-<(triphenylmethyl)oxy>hexane

Base Information

Chemical Name:(2R,4R)-2-methyl-4-<<(4-methylphenyl)sulfonyl>oxy>-6-(phenylthio)-1-<(triphenylmethyl)oxy>hexane
CAS No.:123595-36-8
Molecular Formula:C₃₉H₄₀O₄S₂
Molecular Weight:636.876
Hs Code.:

Synonyms:(2R,4R)-2-methyl-4-<<(4-methylphenyl)sulfonyl>oxy>-6-(phenylthio)-1-<(triphenylmethyl)oxy>hexane

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Chemical Property of (2R,4R)-2-methyl-4-<<(4-methylphenyl)sulfonyl>oxy>-6-(phenylthio)-1-<(triphenylmethyl)oxy>hexane

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Technology Process of (2R,4R)-2-methyl-4-<<(4-methylphenyl)sulfonyl>oxy>-6-(phenylthio)-1-<(triphenylmethyl)oxy>hexane

There total 7 articles about (2R,4R)-2-methyl-4-<<(4-methylphenyl)sulfonyl>oxy>-6-(phenylthio)-1-<(triphenylmethyl)oxy>hexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 128329-10-2
(3R,5R)-5-Methyl-1-phenylsulfanyl-6-trityloxy-hexan-3-ol

: 98-59-9
p-toluenesulfonyl chloride

: 123595-36-8
(2R,4R)-2-methyl-4-<<(4-methylphenyl)sulfonyl>oxy>-6-(phenylthio)-1-<(triphenylmethyl)oxy>hexane

Guidance literature:: With dmap; triethylamine; In dichloromethane; for 18h; Ambient temperature;
DOI:10.1021/ja00169a041

Reference yield:

: 100-68-5
methyl-phenyl-thioether

: 123595-36-8
(2R,4R)-2-methyl-4-<<(4-methylphenyl)sulfonyl>oxy>-6-(phenylthio)-1-<(triphenylmethyl)oxy>hexane

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) n-BuLi, DABCO / 1.) THF, hexane, RT, 45 min, 2.) 0 deg C, 18 h

2: 89 percent / Et₃N, DMAP / CH₂Cl₂ / 18 h / Ambient temperature

With 1,4-diaza-bicyclo[2.2.2]octane; dmap; n-butyllithium; triethylamine; In dichloromethane;
DOI:10.1021/ja00169a041

Reference yield:

: 103233-25-6
(2R,4R)-1,2-epoxy-4-methyl-5-(triphenylmethoxy)pentane

: 123595-36-8
(2R,4R)-2-methyl-4-<<(4-methylphenyl)sulfonyl>oxy>-6-(phenylthio)-1-<(triphenylmethyl)oxy>hexane

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) n-BuLi, DABCO / 1.) THF, hexane, RT, 45 min, 2.) 0 deg C, 18 h

2: 89 percent / Et₃N, DMAP / CH₂Cl₂ / 18 h / Ambient temperature

With 1,4-diaza-bicyclo[2.2.2]octane; dmap; n-butyllithium; triethylamine; In dichloromethane;
DOI:10.1021/ja00169a041