5,15-dibromo-10,20-bis[3,4,5-tris(9-methoxy-1,4,7-trioxanonyl)phenyl]porphyrinatozinc(II)

Base Information

Chemical Name:5,15-dibromo-10,20-bis[3,4,5-tris(9-methoxy-1,4,7-trioxanonyl)phenyl]porphyrinatozinc(II)
CAS No.:1243377-76-5
Molecular Formula:C₇₄H₁₀₂Br₂N₄O₂₄Zn
Molecular Weight:1656.83
Hs Code.:

Synonyms:5,15-dibromo-10,20-bis[3,4,5-tris(9-methoxy-1,4,7-trioxanonyl)phenyl]porphyrinatozinc(II)

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Chemical Property of 5,15-dibromo-10,20-bis[3,4,5-tris(9-methoxy-1,4,7-trioxanonyl)phenyl]porphyrinatozinc(II)

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Technology Process of 5,15-dibromo-10,20-bis[3,4,5-tris(9-methoxy-1,4,7-trioxanonyl)phenyl]porphyrinatozinc(II)

There total 2 articles about 5,15-dibromo-10,20-bis[3,4,5-tris(9-methoxy-1,4,7-trioxanonyl)phenyl]porphyrinatozinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 128-08-5
N-Bromosuccinimide

: 5,15-bis[3,4,5-tris(9-methoxy-1,4,7-trioxanonyl)phenyl]porphyrin

: 557-34-6
zinc diacetate

: 1243377-76-5
5,15-dibromo-10,20-bis[3,4,5-tris(9-methoxy-1,4,7-trioxanonyl)phenyl]porphyrinatozinc(II)

Guidance literature:: In methanol; chloroform; addn. of NBS to CHCl3 soln. of porphyrin deriv. at -40°C, stirring for 60 min, addn. of acetone, evapn., dissolving in CHCl3, treatment with methanolic soln. of zinc compd. for 2 h at room temp.; washing with satd. aq. NaHCO3 and brine, drying over Na2SO4, chromy. (silica gel, CHCl3/methanol (98:2)), NMR and MS;
DOI:10.1039/c004636a

Reference yield:

: C₇₄H₁₀₄Br₂N₄O₂₄

: 1243377-76-5
5,15-dibromo-10,20-bis[3,4,5-tris(9-methoxy-1,4,7-trioxanonyl)phenyl]porphyrinatozinc(II)

Guidance literature:: With zinc diacetate; In methanol; chloroform; at 20 ℃; for 2h;
DOI:10.1039/c004636a

Reference yield: 24.0%

: 1945-84-2
2-ethynylpyridine

: 1243377-76-5
5,15-dibromo-10,20-bis[3,4,5-tris(9-methoxy-1,4,7-trioxanonyl)phenyl]porphyrinatozinc(II)

: 1243377-77-6
5-bromo-15-(2-pyridylethynyl)-10,20-bis[3,4,5-tris(9-methoxy-1,4,7-trioxanonyl)phenyl]porphyrinatozinc(II)

Guidance literature:: With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; triphenyl-arsane; triethylamine; In tetrahydrofuran; at 50 ℃; for 24h; Inert atmosphere; Darkness;
DOI:10.1039/c004636a