N,N,N′,N′-tetrakis(4-carboxyphenyl)-biphenyl-4,4′-diamine

Base Information

Chemical Name:N,N,N′,N′-tetrakis(4-carboxyphenyl)-biphenyl-4,4′-diamine
CAS No.:1193093-31-0
Molecular Formula:C₄₀H₂₈N₂O₈
Molecular Weight:664.671
Hs Code.:

Synonyms:N,N,N′,N′-tetrakis(4-carboxyphenyl)-biphenyl-4,4′-diamine

Suppliers and Price of N,N,N′,N′-tetrakis(4-carboxyphenyl)-biphenyl-4,4′-diamine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemicals and raw materials
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Total 6 raw suppliers

Chemical Property of N,N,N′,N′-tetrakis(4-carboxyphenyl)-biphenyl-4,4′-diamine

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

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Hazard Codes:

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Technology Process of N,N,N′,N′-tetrakis(4-carboxyphenyl)-biphenyl-4,4′-diamine

There total 1 articles about N,N,N′,N′-tetrakis(4-carboxyphenyl)-biphenyl-4,4′-diamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 124-38-9,18923-20-1
carbon dioxide

: 113664-24-7
N,N,N′,N′-tetrakis(4-bromophenyl)[1,1′-biphenyl]-4,4′-diamine

: 1193093-31-0
N,N,N′,N′-tetrakis(4-carboxyphenyl)-biphenyl-4,4′-diamine

Guidance literature:: N,N,N′,N′-tetrakis(4-bromophenyl)[1,1′-biphenyl]-4,4′-diamine; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃;

carbon dioxide; In tetrahydrofuran; hexane; at -78 ℃; crushed dry ice was added;

With acetic acid; In tetrahydrofuran; hexane;
DOI:10.1002/chem.201001549

Reference yield: 62.0%

: zinc nitrate tetrahydrate

: 1193093-31-0
N,N,N′,N′-tetrakis(4-carboxyphenyl)-biphenyl-4,4′-diamine

: (N,N,N',N'-benzidinetetrabenzoate)diaquadizinc(II)

Guidance literature:: With glacial acetic acid; In N,N-dimethyl-formamide; Sonication; Zn nitrate and ligand (10:1) dissolved in DMF by sonication for 1 min, treated with 1 drop of glacial acetic acid, heated to 353 K for 48 h, mother liquor exchanged by fresh DMF, heated to 353 K for 24 h; filtered (Ar), washed (DMF), dried (vac.), elem. anal.;
DOI:10.1002/ejic.201000415

Reference yield: 40.0%

: copper(II) nitrate trihydrate

: 1193093-31-0
N,N,N′,N′-tetrakis(4-carboxyphenyl)-biphenyl-4,4′-diamine

: (N,N,N',N'-benzidinetetrabenzoate)diaquadicopper(II)

Guidance literature:: With HNO₃; In N,N-dimethyl-formamide; Sonication; Cu nitrate and ligand (10:1) dissolved in DMF by sonication for 1 min, treated with 1 drop of concd.HNO3, heated to 353 K for 48 h; mother liquor decanted, replaced by fresh DMF, washed (DMF), filtered (Ar), washed (DMF), dried (vac.), elem. anal.;
DOI:10.1002/ejic.201000415