(2R,3S,4R,6R)-3,4-bisbenzyloxy-2-benzyloxymethyl-6-phenyltetrahydropyran

Base Information

Chemical Name:(2R,3S,4R,6R)-3,4-bisbenzyloxy-2-benzyloxymethyl-6-phenyltetrahydropyran
CAS No.:1607469-27-1
Molecular Formula:C₃₃H₃₄O₄
Molecular Weight:494.631
Hs Code.:

Synonyms:(2R,3S,4R,6R)-3,4-bisbenzyloxy-2-benzyloxymethyl-6-phenyltetrahydropyran

Suppliers and Price of (2R,3S,4R,6R)-3,4-bisbenzyloxy-2-benzyloxymethyl-6-phenyltetrahydropyran

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2R,3S,4R,6R)-3,4-bisbenzyloxy-2-benzyloxymethyl-6-phenyltetrahydropyran

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Technology Process of (2R,3S,4R,6R)-3,4-bisbenzyloxy-2-benzyloxymethyl-6-phenyltetrahydropyran

There total 4 articles about (2R,3S,4R,6R)-3,4-bisbenzyloxy-2-benzyloxymethyl-6-phenyltetrahydropyran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 1607469-24-8
(2R,3S,4S,5S,6S)-3,4-bis(benzyloxy)-2-(benzyloxymethyl)-6-phenyl-5-(phenylselanyl)tetrahydro-2H-pyran

: 1607469-27-1
(2R,3S,4R,6R)-3,4-bisbenzyloxy-2-benzyloxymethyl-6-phenyltetrahydropyran

Guidance literature:: With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In benzene; at 80 ℃; for 12h; Sealed tube; Inert atmosphere;
DOI:10.1021/jo500730y

Reference yield:

: 1607468-93-8
(2R,3R,4R,E)-1,3,4-tris(benzyloxy)-6-(o-tolyl)hex-5-en-2-ol

: 1607469-27-1
(2R,3S,4R,6R)-3,4-bisbenzyloxy-2-benzyloxymethyl-6-phenyltetrahydropyran

Guidance literature:: Multi-step reaction with 2 steps

1: dichloromethane / 4 h / -78 °C / Inert atmosphere

2: tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) / benzene / 12 h / 80 °C / Sealed tube; Inert atmosphere

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In dichloromethane; benzene;
DOI:10.1021/jo500730y

Reference yield:

: 55628-54-1
3,4,6-tri-O-benzyl-D-glucal

: 1607469-27-1
(2R,3S,4R,6R)-3,4-bisbenzyloxy-2-benzyloxymethyl-6-phenyltetrahydropyran

Guidance literature:: Multi-step reaction with 3 steps

1: bis(acetylacetonate)nickel(II); potassium carbonate / toluene / 1.5 h / 170 °C / Molecular sieve; Microwave irradiation; Inert atmosphere

2: dichloromethane / 4 h / -78 °C / Inert atmosphere

3: tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) / benzene / 12 h / 80 °C / Sealed tube; Inert atmosphere

With bis(acetylacetonate)nickel(II); 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; potassium carbonate; In dichloromethane; toluene; benzene;
DOI:10.1021/jo500730y