Benzoic acid (4E,6E)-(3S,9S)-3,9-bis-(tert-butyl-dimethyl-silanyloxy)-6-methyl-10-oxo-deca-4,6-dienyl ester

Base Information

Chemical Name:Benzoic acid (4E,6E)-(3S,9S)-3,9-bis-(tert-butyl-dimethyl-silanyloxy)-6-methyl-10-oxo-deca-4,6-dienyl ester
CAS No.:328381-85-7
Molecular Formula:C₃₀H₅₀O₅Si₂
Molecular Weight:546.895
Hs Code.:

Synonyms:Benzoic acid (4E,6E)-(3S,9S)-3,9-bis-(tert-butyl-dimethyl-silanyloxy)-6-methyl-10-oxo-deca-4,6-dienyl ester

Suppliers and Price of Benzoic acid (4E,6E)-(3S,9S)-3,9-bis-(tert-butyl-dimethyl-silanyloxy)-6-methyl-10-oxo-deca-4,6-dienyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Benzoic acid (4E,6E)-(3S,9S)-3,9-bis-(tert-butyl-dimethyl-silanyloxy)-6-methyl-10-oxo-deca-4,6-dienyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Benzoic acid (4E,6E)-(3S,9S)-3,9-bis-(tert-butyl-dimethyl-silanyloxy)-6-methyl-10-oxo-deca-4,6-dienyl ester

There total 7 articles about Benzoic acid (4E,6E)-(3S,9S)-3,9-bis-(tert-butyl-dimethyl-silanyloxy)-6-methyl-10-oxo-deca-4,6-dienyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 328381-91-5
Benzoic acid (4E,6E)-(3S,9S)-3,9-bis-(tert-butyl-dimethyl-silanyloxy)-10-hydroxy-6-methyl-deca-4,6-dienyl ester

: 328381-85-7
Benzoic acid (4E,6E)-(3S,9S)-3,9-bis-(tert-butyl-dimethyl-silanyloxy)-6-methyl-10-oxo-deca-4,6-dienyl ester

Guidance literature:: With Dess-Martin periodane; In dichloromethane;
DOI:10.1002/1521-3773(20001215)39:24<4612::AID-ANIE4612>3.0.CO;2-C

Reference yield:

: 328381-90-4
benzoic acid 3-(tert-butyl-dimethyl-silanyloxy)-4-oxo-butyl ester

: 328381-85-7
Benzoic acid (4E,6E)-(3S,9S)-3,9-bis-(tert-butyl-dimethyl-silanyloxy)-6-methyl-10-oxo-deca-4,6-dienyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: LDA / tetrahydrofuran / 0.08 h / -78 °C

1.2: 57 percent / tetrahydrofuran / 3 h / -78 - 20 °C

2.1: 76 percent / Dess-Martin periodinane; MaHCO₃ / CH₂Cl₂

With Dess-Martin periodane; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane; 2.1: Dess-Martin oxidation;
DOI:10.1002/1521-3773(20001215)39:24<4612::AID-ANIE4612>3.0.CO;2-C

Reference yield:

: 328381-98-2
(S)-3-((tert-butyldimethylsilyl)oxy)-4-hydroxybutyl benzoate

: 328381-85-7
Benzoic acid (4E,6E)-(3S,9S)-3,9-bis-(tert-butyl-dimethyl-silanyloxy)-6-methyl-10-oxo-deca-4,6-dienyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: 91 percent / (COCl)2; DMSO; NEt₃ / CH₂Cl₂ / -78 °C

2.1: LDA / tetrahydrofuran / 0.08 h / -78 °C

2.2: 57 percent / tetrahydrofuran / 3 h / -78 - 20 °C

3.1: 76 percent / Dess-Martin periodinane; MaHCO₃ / CH₂Cl₂

With oxalyl dichloride; Dess-Martin periodane; dimethyl sulfoxide; triethylamine; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane; 1.1: Swern oxidation / 3.1: Dess-Martin oxidation;
DOI:10.1002/1521-3773(20001215)39:24<4612::AID-ANIE4612>3.0.CO;2-C