amyl(5,10,15,20-tetramesitylporphyrinato)rhodium(III)

Base Information

• Chemical Name: amyl(5,10,15,20-tetramesitylporphyrinato)rhodium(III)
• CAS No.: 1201111-97-8
• Molecular Formula: C₆₁H₆₃N₄Rh
• Molecular Weight: 955.104
• Mol file: 1201111-97-8.mol

Synonyms:amyl(5,10,15,20-tetramesitylporphyrinato)rhodium(III)

Chemical Property of amyl(5,10,15,20-tetramesitylporphyrinato)rhodium(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of amyl(5,10,15,20-tetramesitylporphyrinato)rhodium(III)

There total 3 articles about amyl(5,10,15,20-tetramesitylporphyrinato)rhodium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

(5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) iodide (85990-32-5) + dihexyl ether (112-58-3) → amyl(5,10,15,20-tetramesitylporphyrinato)rhodium(III) (1201111-97-8)

Guidance literature:

With KOH; In further solvent(s); reaction of rhodium compd. with dihexyl ether in presence of 10 equiv. of KOH at 100°C for 1 d under N2;

DOI:10.1021/om900270v

Reference yield: 54.0%

5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II) (121393-39-3) + dihexyl ether (112-58-3) → hexyl formate (629-33-4) + amyl(5,10,15,20-tetramesitylporphyrinato)rhodium(III) (1201111-97-8)

Guidance literature:

With water; tetraphenylphosphonium bromide; triphenylphosphine; potassium hydroxide; at 25 ℃; for 2h; regioselective reaction; Inert atmosphere; Darkness;

DOI:10.1021/om200280w

Reference yield: 54.0%

5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II) (121393-39-3) + dihexyl ether (112-58-3) → amyl(5,10,15,20-tetramesitylporphyrinato)rhodium(III) (1201111-97-8)

Guidance literature:

With PPh₃; KOH; Ph₄PBr; In further solvent(s); under N2; in the dark; Rh compd. reacted with (C6H13)2O in presence of PPh3 (1 equiv.), KOH (10 equiv.), H2O (50 equiv.) and Ph4PBr (0.1 equiv.)at 25°C for 2 h;

DOI:10.1021/om200280w

upstream raw materials:

(5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) iodide

dihexyl ether

5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II)