Iodorhodium(III) Tetramesitylporphyrin

Base Information

• Chemical Name: Iodorhodium(III) Tetramesitylporphyrin
• CAS No.: 85990-32-5
• Molecular Formula: C56H54IN4Rh++
• Molecular Weight: 1010.87
• Mol file: 85990-32-5.mol

Synonyms:Iodorhodium(III) Tetramesitylporphyrin

Chemical Property of Iodorhodium(III) Tetramesitylporphyrin

Chemical Property:

• PSA: 45.44000
• LogP: 8.11210

Purity/Quality:

98.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Iodorhodium(III) Tetramesitylporphyrin

There total 4 articles about Iodorhodium(III) Tetramesitylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

(5,10,15,20-tetramesitylporphyrinato)rhodium(III) hydride (124535-65-5) + iodine (7553-56-2,12190-71-5,8031-47-8) → (5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) iodide (85990-32-5)

Guidance literature:

With 2,2,6,6-tetramethylpiperidine-1-oxyl; In benzene; byproducts: 2,2,6,6-tetramethylpiperidine-1-ol; piperidyl-compound was added to a soln. of complex in C6H6 under N2, themixt. was stirred at room temp. for 30 min, an excess of iodine was add ed; column chromy.;

DOI:10.1021/ja078157f

Reference yield: 51.0%

(5,10,15,20-tetramesitylporphyrinato)rhodium(III) chloride (161407-97-2) + methyl iodide (74-88-4) → (5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate)rhodium(III) methyl + (5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) iodide (85990-32-5)

Guidance literature:

With potassium hydroxide; In water; benzene; at 120 ℃; for 84h; Darkness;

DOI:10.1021/acs.organomet.5b00488

Reference yield: 50.0%

di(rhodium)tetracarbonyl dichloride + iodine (7553-56-2,12190-71-5,8031-47-8) + 5,10,15,20-tetramesitylporphyrin (56396-12-4) → (5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) iodide (85990-32-5)

Guidance literature:

di(rhodium)tetracarbonyl dichloride; 5,10,15,20-tetramesitylporphyrin; With sodium acetate; In 1,2-dichloro-ethane; at 80 ℃; for 48h; Inert atmosphere; Schlenk technique;

iodine; In 1,2-dichloro-ethane; at 20 ℃;

DOI:10.1021/jacs.8b03029

upstream raw materials:

(5,10,15,20-tetramesitylporphyrinato)rhodium(III) hydride

iodine

(5,10,15,20-tetramesitylporphyrinato)rhodium(III) chloride

methyl iodide

Downstream raw materials:

(5,10,15,20-tetramesitylporphyrinato)rhodium(III) hydride

(5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) ethyl

[Rh(5,10,15,20-tetramesitylporphyrinato)SiPhMeH]

[Rh(5,10,15,20-tetramesitylporphyrinato)SiEt₃]