{2,5-diphenyl-3,4-bis(4-methoxyphenyl)cyclopentadienone}tricarbonylruthenium⁽⁰⁾

Base Information

• Chemical Name: {2,5-diphenyl-3,4-bis(4-methoxyphenyl)cyclopentadienone}tricarbonylruthenium⁽⁰⁾
• CAS No.: 135853-90-6
• Molecular Formula: C₃₄H₂₄O₆Ru
• Molecular Weight: 629.631
• Mol file: 135853-90-6.mol

Synonyms:{2,5-diphenyl-3,4-bis(4-methoxyphenyl)cyclopentadienone}tricarbonylruthenium⁽⁰⁾

Chemical Property of {2,5-diphenyl-3,4-bis(4-methoxyphenyl)cyclopentadienone}tricarbonylruthenium⁽⁰⁾

Chemical Property:

Purity/Quality:

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• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of {2,5-diphenyl-3,4-bis(4-methoxyphenyl)cyclopentadienone}tricarbonylruthenium⁽⁰⁾

There total 2 articles about {2,5-diphenyl-3,4-bis(4-methoxyphenyl)cyclopentadienone}tricarbonylruthenium⁽⁰⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

dodecacarbonyl-triangulo-triruthenium (15243-33-1) + 3,4-bis(4-methoxyphenyl)-2,5-diphenyl-2,4-cyclopentadien-1-one (668-29-1) → [3,4-(p-MeOPh)2-2,5-Ph2(η4-C4CO)]Ru(CO)3 (135853-90-6)

Guidance literature:

In toluene; at 110 ℃; for 48h; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.jorganchem.2017.05.039

Reference yield: 70.0%

dodecacarbonyl-triangulo-triruthenium (15243-33-1) + 3,4-bis(4-methoxyphenyl)-2,5-diphenyl-2,4-cyclopentadien-1-one (668-29-1) → {2,5-diphenyl-3,4-bis(4-methoxyphenyl)cyclopentadienone}tricarbonylruthenium(0) (135853-90-6)

Guidance literature:

In toluene; placed in a reactor, purged with N2, closed, heated at 150°C for 24 h, cooled to ambient temp., soln. purged with N2, , closed and reheated at the above temp. for 5 h, cooled to room temp.; solvent removed in vac., residue dissolved in CH2Cl2, passed through a silica column, elution with CH2Cl2; elem. anal.;

DOI:10.1021/om00057a019

Reference yield: 75.0%

{2,5-diphenyl-3,4-bis(4-methoxyphenyl)cyclopentadienone}tricarbonylruthenium(0) (135853-90-6) → {2,5-(C6H5)2-3,4-(4-MeOC6H4)2C4CO}2H(μ-H)(CO)4Ru2 (135853-87-1)

Guidance literature:

With sodium carbonate; In acetone; (N2), stirred at room temp. for 30 min., neutralized with saturated NH4Cl-soln.; solvent removed in vac., residue extracted with methylene chloride, filtered, solvent removed in vac., chromy.(silica column, petzroleum ether(60-80), CH2Cl:petroleum ether(1:1)); elem. anal.;

DOI:10.1021/om00057a019

upstream raw materials:

dodecacarbonyl-triangulo-triruthenium

3,4-bis(4-methoxyphenyl)-2,5-diphenyl-2,4-cyclopentadien-1-one

Downstream raw materials:

{2,5-(C6H5)2-3,4-(4-MeOC6H4)2C4CO}2H(μ-H)(CO)4Ru2