[Ca((2,6-diisopropylphenyl)NC(CH₃)CHC(CH₃)N(2,6-diisopropylphenyl))(N(SiMe₃)2)(THF)]

Base Information

• Chemical Name: [Ca((2,6-diisopropylphenyl)NC(CH₃)CHC(CH₃)N(2,6-diisopropylphenyl))(N(SiMe₃)2)(THF)]
• CAS No.: 505028-44-4
• Molecular Formula: C₃₉H₆₇CaN₃OSi₂
• Molecular Weight: 690.229
• Mol file: 505028-44-4.mol

Synonyms:[Ca((2,6-diisopropylphenyl)NC(CH₃)CHC(CH₃)N(2,6-diisopropylphenyl))(N(SiMe₃)2)(THF)]

Chemical Property of [Ca((2,6-diisopropylphenyl)NC(CH₃)CHC(CH₃)N(2,6-diisopropylphenyl))(N(SiMe₃)2)(THF)]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of [Ca((2,6-diisopropylphenyl)NC(CH₃)CHC(CH₃)N(2,6-diisopropylphenyl))(N(SiMe₃)2)(THF)]

There total 1 articles about [Ca((2,6-diisopropylphenyl)NC(CH₃)CHC(CH₃)N(2,6-diisopropylphenyl))(N(SiMe₃)2)(THF)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + potassium hexamethylsilazane (40949-94-8) + 2-((2,6-diisopropylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene → [Ca((2,6-diisopropylphenyl)NC(CH3)CHC(CH3)N(2,6-diisopropylphenyl))(N(SiMe3)2)(THF)] (505028-44-4)

Guidance literature:

With calcium iodide; for 12h; Inert atmosphere;

DOI:10.1021/ja9003377

Reference yield: 72.0%

[Ca((2,6-diisopropylphenyl)NC(CH3)CHC(CH3)N(2,6-diisopropylphenyl))(N(SiMe3)2)(THF)] (505028-44-4) + dimethylamine borane (74-94-2) → C35H58BCaN3O (1246355-45-2)

Guidance literature:

In hexane; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1002/chem.201000127

Reference yield: 71.0%

N,N-Dimethylpropargylamin (7223-38-3) + [Ca((2,6-diisopropylphenyl)NC(CH3)CHC(CH3)N(2,6-diisopropylphenyl))(N(SiMe3)2)(THF)] (505028-44-4) → [Ca((2,6-diisopropylphenyl)NC(CH3)CHC(CH3)N(2,6-diisopropylphenyl))(CCCH2N(CH3)2)]2

Guidance literature:

In toluene; at 20 ℃; for 2h; Schlenk technique; Inert atmosphere;

DOI:10.1021/om400678d

upstream raw materials:

tetrahydrofuran

potassium hexamethylsilazane

Downstream raw materials:

C₃₅H₅₈BCaN₃O

[HC{(Me)CN(2,6-iPr₂C₆H₃)}2Ca{N(CH₂)4BH₃}-(THF)]

C₃₂H₅₂BCaN₃

C₂₉H₅₂BCaN₅