74-94-2

Basic information

• Product Name: Dimethylaminoborane
• Synonyms: dimethylamine,compd.withborane(1:1);dimethylamineborane(1:1);Methanamine, N-methyl-, compd. with borane (1:1);n-methyl-methanamincompd.withborane(1:1);n-methylmethanaminecompd.withborane(1:1);trihydro(N-methylmethanamine)-,(T-4)-Boron;DMAB;DIMETHYLAMINE BORANE
• CAS NO: 74-94-2
• Molecular Formula: C₂H₁₀BN
• Molecular Weight: 58.92
• EINECS: 200-823-7
• Product Categories: Organometallics;B (Classes of Boron Compounds);Boranes;Reduction;Synthetic Organic Chemistry;organoboron and borato-metal complexes
• Mol File: 74-94-2.mol
• Article Data: 24

Chemical Properties

• Melting Point: 36 °C(lit.)
• Boiling Point: 59-65°C 12mm
• Flash Point: 110 °F
• Appearance: White to yellow/Flakes or Granules
• Density: 0,69 g/cm3
• Vapor Pressure: 1520mmHg at 25°C
• Storage Temp.: 0-6°C
• Solubility: 120g/l
• Water Solubility: 125 g/L (20 ºC)
• Sensitive: Air & Moisture Sensitive
• Stability: Stable, but water sensitive. Contact with water releases very flammable gases. Incompatible with acids, halogens, oxidizing agen
• CAS DataBase Reference: Dimethylaminoborane(CAS DataBase Reference)
• NIST Chemistry Reference: Dimethylaminoborane(74-94-2)
• EPA Substance Registry System: Dimethylaminoborane(74-94-2)

Safety Data

• Hazard Codes: F,T
• Statements: 11-24/25-36/37/38-20
• Safety Statements: 16-28-36/37-45-36-33-15
• RIDADR: UN 2926 4.1/PG 2
• WGK Germany: 2
• RTECS: IP9450000
• F: 10
• TSCA: Yes
• HazardClass: 4.1
• PackingGroup: II
• Hazardous Substances Data: 74-94-2(Hazardous Substances Data)

Usage

Chemical Properties

white crystalline powder with an amine odour

Uses

Different sources of media describe the Uses of 74-94-2 differently. You can refer to the following data:
1. Borane-dimethylamine complex is used in a nickel-catalyzed reduction of electron-deficient aryl tosylates. It also serves as a reducing agent in electrolytic deposition of metals, alloys, semiconductors and insulators.
2. Reagent used in a Ni-catalyzed reduction of electron-deficient aryl tosylates. The catalyst is composed of commercially available Ni(PPh3)2Cl2(529621) and PCy3(261971).

Safety Profile

Poison by ingestion, intraperitoneal, and intravenous routes. A skin and eye irritant. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also DIMETHYLAMINE and BORANE.

InChI:InChI=1/C2H7N.B/c1-3-2;/h3H,1-2H3;

Synthetic route

sodium tetrahydroborate (16940-66-2) + dimethylammonium salt → dimethylamine borane (74-94-2)

Conditions	Yield
In tetrahydrofuran at 20℃; for 4h;	93%

dimethyl amine (124-40-3) + diborane (19287-45-7) → dimethylamine borane (74-94-2)

Conditions	Yield
In neat (no solvent) excess amine, 30-40°C, concn. of soln.;; distn. in vac. (60°C/2Torr) or recrystn. (petroleum ether);;	91%
In neat (no solvent) excess amine, 30-40°C, concn. of soln.;; distn. in vac. (60°C/2Torr) or recrystn. (petroleum ether);;	91%
In diethyl ether product in liquid form, crystn. on standing;; distn. in vac.;;	961 %
In gas determination of react.-enthalpy;;
for 2h; Inert atmosphere; Gas phase; Cooling with ice;

sodium tetrahydroborate (16940-66-2) + dimethyl amine (124-40-3) → dimethylamine borane (74-94-2)

Conditions	Yield
With iodine In 1,2-dimethoxyethane byproducts: NaI, H2; dropwise addn. of NaBH4 and I2 in DME to amine in DME, removal of solvent, addn. of C6H6, filtration, evapn. of filtrate in a N2 stream, drying in vac.;; recrystn. from CH2Cl2/hexane mixture;;	84.4%
With potassium dihydrogenphosphate In water at -20 - 5℃; for 10h; Solvent; Reagent/catalyst; Autoclave; Large scale;	84.5%
With boron trifluoride diethyl etherate In tetrahydrofuran refluxing, filtartion, evapn. of solvent;;

N,N-dimethylammonium chloride (506-59-2) → dimethylamine borane (74-94-2)

Conditions	Yield
With sodium tetrahydroborate In 1,2-dimethoxyethane at 20℃; Cooling with ice;	71%
With lithium borohydride In diethyl ether at -78 - 20℃;

lithium borohydride + N,N-dimethylammonium chloride (506-59-2) → dimethylamine borane (74-94-2)

Conditions	Yield
In neat (no solvent) in vac., 3h;; distn. in vac. at 75-76°C/0.5Torr;;	70%
In diethyl ether byproducts: H2, LiCl; room temp., 3h, filtration, evapn.;; recrystn. from C6H6/petroleum ether;;
In diethyl ether amine hydrochloride was added at -78°C to soln. LiBH4 in Et2O andstirred for 30 min, allowed to warm to room temp. and stirred for 5 h; react. mixt. was cooled to -45°C, slvent was removed in vacuo, residue was heated in vacuo at 65°C for sublimation;

potassium borohydride + N,N-dimethylammonium chloride (506-59-2) → dimethylamine borane (74-94-2)

Conditions	Yield
With sodium hydroxide In 1,2-dimethoxyethane; water at -5 - 15℃; for 6 - 10h; Conversion of starting material;	55.1%
With sodium hydroxide In tetrahydrofuran; water at -10 - 15℃; for 10 - 14h; Conversion of starting material;	54%

Me3N*BH2SPh + dimethyl amine (124-40-3) → dimethylamine borane (74-94-2) + Me2NH*BH2SPh (1387442-05-8)

Conditions	Yield
at 20℃; for 36h;	A 10% B 46%

dimethylamine borane (1838-13-7) + lithium borohydride → dimethylamine borane (74-94-2)

Conditions	Yield
In tetrahydrofuran; water at 20℃; for 4h; Inert atmosphere;	10%

calcium borohydride + dimethyl amine (124-40-3) → dimethylamine borane (74-94-2)

Conditions	Yield
In tetrahydrofuran

boron trioxide + hydrogen (1333-74-0) + dimethyl amine (124-40-3) → dimethylamine borane (74-94-2)

Conditions	Yield
With aluminium trichloride; aluminium In neat (no solvent) High Pressure; heating the mixture under a H2-pressure of 800-900kg/cm**2 to 273°C for 10h; in mixture with other products;;

sodium dimethylamidotrihydridoborate + water (7732-18-5) → dimethylamine borane (74-94-2)

Conditions	Yield
In hydrogenchloride hydrolysis with 0.05n HCl, equilibrium;;

sodium tetrahydroborate (16940-66-2) + dimethylammonium dihydrogen phosphate (23307-08-6) → dimethylamine borane (74-94-2)

Conditions	Yield
In neat (no solvent) heating; dissolving in (CH3)2NH2;; evapn. in vac. or recrystn. (petroleum ether);;

dimethylamine borane (1838-13-7) → dimethylamine borane (74-94-2)

Conditions	Yield
With pyrographite In not given with C generated in an electric arc; further by-products;;

dimethylamine borane (1838-13-7) + methylamine (74-89-5) → dimethylamine borane (74-94-2)

Conditions	Yield
In tetrahydrofuran byproducts: HB{N(CH3)2}(NHCH3);
In cyclohexane byproducts: HB{N(CH3)2}(NHCH3);

dimethylamine borane (1838-13-7) + N,N',N''-triethylborazane (26200-45-3, 7270-53-3, 26200-44-2) → dimethylamine borane (74-94-2)

Conditions	Yield
In neat (no solvent) byproducts: (HBNC2H5)3; on heating;;

dimethylamine borane (1838-13-7) + N,N',N''-tripropylborazane (26200-46-4, 26200-47-5) → dimethylamine borane (74-94-2)

Conditions	Yield
In neat (no solvent) byproducts: (HB-N-n-C3H7)3; on heating;;

dimethylamine borane (1838-13-7) + N,N',N''-triisopropylborazane (272443-95-5) → dimethylamine borane (74-94-2)

Conditions	Yield
In neat (no solvent) byproducts: (HB-N-i-C3H7)3; on heating;;

dimethyl amine (124-40-3) + diborane (19287-45-7) → [H2B((CH3)2NH)2](1+)*[BH4](1-)=[H2B((CH3)2NH)2][BH4] + dimethylamine borane (74-94-2)

Conditions	Yield
In neat (no solvent) prepared by condensing diborane in small portions to the amine until anexcess of diborane is present as indicated by the vapour pressure; detected by (13)C-NMR;

lithium borohydride + N,N-dimethylaminodichlorophosphane (683-85-2) → dimethylamine borane (74-94-2)

Conditions	Yield
In neat (no solvent) at 80°C in mixture with other products;;

phosphine-borane (19121-56-3) + dimethyl amine (124-40-3) → dimethylamine borane (74-94-2)

Conditions	Yield
In neat (no solvent) byproducts: {(CH3)2NH2}{H2P{BH3)2}; < -45°C, at higher temp. formation of ionic by-product; discussion of mechanism;;

lithium borohydride + N,N-dimethyl-formamide (68-12-2, 33513-42-7) → dimethylamine borane (74-94-2) + trimethylamine-borane (75-22-9)

Conditions	Yield
In N,N-dimethyl-formamide soln. of LiBH4 in DMF under dry, oxygen free N2 (after 7 ds at ambient temp.); not isolated; (11)B-NMR;

trimethylamine-borane (75-22-9) + dimethyl amine (124-40-3) → dimethylamine borane (74-94-2)

Conditions	Yield
In neat (no solvent) excess amine, room temp.;;

P(BH3)F3 (14931-39-6) + dimethyl amine (124-40-3) → dimethylamine borane (74-94-2)

Conditions	Yield
In diethyl ether byproducts: PF3; excess amine;;

triethylamine-borane (1722-26-5) + dimethyl amine (124-40-3) → dimethylamine borane (74-94-2)

Conditions	Yield
In neat (no solvent) excess amine, room temp.;;

N,N',N''-triisopropylborazane (272443-95-5) + H2BN(CH3)2*2H2B-NH-(i-C3H7) → dimethylamine borane (74-94-2)

Conditions	Yield
In neat (no solvent) byproducts: (HB-N-i-C3H7)3; on heating;;

H3BCO*2NH(CH3)2 → dimethylamine borane (74-94-2)

Conditions	Yield
byproducts: (CH3)2NH, CO; at room temp.;;
byproducts: (CH3)2NH, CO; at room temp.;;

{(CH3)2N}F2PBH3 + dimethyl amine (124-40-3) → dimethylamine borane (74-94-2)

Conditions	Yield
In diethyl ether byproducts: (CH3)2NPF2; very slow react.;;

bis(dimethylamino)phosphine borane → dimethylamine borane (74-94-2)

Conditions	Yield
byproducts: H2, HB{N(CH3)2}2; at 65°C;;

{Cd(NH3)6}(2+)*2{BH4}(1-)={Cd(NH3)6}{BH4}2 + dimethyl amine (124-40-3) → dimethylamine borane (74-94-2)

Conditions	Yield
With hydrogen sulfide In neat (no solvent) treatment with H2S; filtration, removal of excess amine;; distn. or treatment with activated coal in ether;;	>99
With hydrogen sulfide In neat (no solvent) treatment with H2S; filtration, removal of excess amine;; distn. or treatment with activated coal in ether;;	>99

(CH3)2AsN(CH3)2BH3 (106587-23-9) + dimethylarsine (593-57-7) → tetramethyldiarsine (471-35-2) + dimethylamine borane (74-94-2)

Conditions	Yield
In (2)H8-toluene Me2AsH is condensed onto the frozen soln. of B-compd. (-196°C) in a NMR-tube, sealing of the tube, agitating at -95°C, reaction is studied from -80 to -10°C; monitored by NMR-spectroscopy;

dimethylamine borane (74-94-2) → hydrogen (1333-74-0)

Conditions	Yield
With [IrH2{(P(phenyl)2(o-C6H4CO))2H}] In tetrahydrofuran; water for 0.133333h; Catalytic behavior; Kinetics; Thermodynamic data; Reagent/catalyst;	100%
With ethanol; ReBr2(NO)(CH3CN)(PTA)2 In ethanol Kinetics; byproducts: B(OC2H5)3, (CH3)2NH; ethanolysis of amine-borane with 1 mol.-% ReBr2(NO)(MeCN)(1,3,5-triaza-7-phosphaadamantane)2 at room temp. or at 50°C;
With ethanol In ethanol byproducts: B(OC2H5)3, (CH3)2NH; ethanolysis of amine-borane at 50°C;

dimethylamine borane (74-94-2) → cyclic(dimethylamino borane) dimer (23884-11-9)

Conditions	Yield
With N-benzylidene tert-butylamine; C28H24BF12P In benzene at 25℃; for 6h; Temperature;	99%
With 2,2,6,6-tetramethyl-piperidine; trimethylsilyl trifluoromethanesulfonate In 1,2-dichloro-benzene at 20℃; for 2h; Inert atmosphere;	89%
With Mes2P-C{=C(H)-Ph}-AltBu2 at 45 - 90℃; Catalytic behavior; Concentration; Time;	77%

dimethylamine borane (74-94-2) + benzoic acid (65-85-0) → N,N-dimethylbenzamide (611-74-5)

Conditions	Yield
In 5,5-dimethyl-1,3-cyclohexadiene for 12h; Reflux;	99%

dimethylamine borane (74-94-2) + hexanoic acid (142-62-1) → N,N-dimethylhexanamide (5830-30-8)

Conditions	Yield
In 5,5-dimethyl-1,3-cyclohexadiene for 12h; Reflux;	98%

dimethylamine borane (74-94-2) + Trimethylacetic acid (75-98-9) → Tripivaloyloxyboran-dimethylamin-Addukt

Conditions	Yield
In 5,5-dimethyl-1,3-cyclohexadiene at 100℃; for 4h;	98%

1,4-dioxane (123-91-1) + n-butyllithium (109-72-8, 29786-93-4) + dimethylamine borane (74-94-2) → lithium (dimethylamino)hydroborate, adduct with 1,4-dioxane

Conditions	Yield
In hexane byproducts: butane; (anhydrous conditions); dissoln. of BH3*NHMe2 in 1,4-dioxane, after cooling in an ice-bath addn. of n-BuLi in hexane within 1 h with stirring, further stirring at room temp. for 2 h; crystn. (toluene); elem. anal.;	97%

dimethylamine borane (74-94-2) → dimethylamine borane (1838-13-7)

Conditions	Yield
With tri-tert-butyl phosphine; tris(pentafluorophenyl)borate In C6D5Cl for 24h;	97%
With phenylmagnesium bromide In tetrahydrofuran at 20℃; for 5h; Inert atmosphere;	6%
With bis(cyclopentadienyl)titanium dichloride; n-butyllithium In toluene at 20℃; for 20h; Inert atmosphere;

n-butyllithium (109-72-8, 29786-93-4) + dimethylamine borane (74-94-2) → lithium (dimethylamino)hydroborate + tris(dimethylamino)borane (4375-83-1) + Dimethylamino-di-n-butyl-boran (7289-86-3) + Li{B(n-C4H9)4} (15243-31-9)

Conditions	Yield
In hexane byproducts: butane; (anhydrous conditions); stirring (4 h); centrifugation, washing (hexane), drying (vac.); elem. anal.;	A 96% B n/a C n/a D n/a

dimethylamine borane (74-94-2) + C19H42BFeN3P2 + sodium tetraphenyl borate (143-66-8) → C21H46BFeN4P2(1+)*C24H20B(1-)

Conditions	Yield
With N,N-dimethylammonium chloride In tetrahydrofuran at 50℃; for 18h; Inert atmosphere;	96%

1-indoline (496-15-1) + dimethylamine borane (74-94-2) → 1-borylindoline (1355176-05-4)

Conditions	Yield
In neat (no solvent) byproducts: H2; (inert atm., Schlenk technique); heating mixt. of 1 equiv. of indoline and 1 equiv. of borane deriv. at 100°C under Ar flow; extn. (CHCl3), filtration through celite, evapn., washing with hexanes, NMR and IR;	95%
With catalyst: Pd/C In neat (no solvent) byproducts: H2, (CH3)2NH; (inert atm., Schlenk technique); heating mixt. of 1 equiv. of indoline, 1 equiv. of borane deriv. and Pd/C at 100°C for 2 h under Ar flow; extn. (CHCl3), filtration through celite, evapn., washing with hexanes, NMR and IR;	87%

dimethylamine borane (74-94-2) + [(2,6-(t-Bu2PO)2C5H3N)Rh(H2)][tetrakis(3,5-bis(trifluoromethyl)phenyl)borate] (1361399-35-0) → C23H49BN2O2P2Rh(1+)*C32H12BF24(1-)

Conditions	Yield
Inert atmosphere;	95%

n-butyllithium (109-72-8, 29786-93-4) + dimethylamine borane (74-94-2) → lithium (dimethylamino)hydroborate

Conditions	Yield
Stage #1: n-butyllithium; dimethylamine borane In hexane at -78℃; for 1h; Inert atmosphere; Stage #2: In hexane at 20℃; for 1h; Inert atmosphere;	94%

dimethylchloroamine (1585-74-6) + dimethylamine borane (74-94-2) → (bisdimethylamine)dihydroboronium(+) chloride

Conditions	Yield
In tetrachloromethane dropwise addn. of (CH3)2NCl in CCl4, pptn.;;	92%

dimethylamine borane (74-94-2) + Cyclohexanecarboxylic acid (98-89-5) → N,N-dimethylcyclohexanecarboxamide (17566-51-7)

Conditions	Yield
In 5,5-dimethyl-1,3-cyclohexadiene for 12h; Reflux;	92%

dimethylamine borane (74-94-2) → bis(dimethylamino)borane (2386-98-3) + cyclic(dimethylamino borane) dimer (23884-11-9)

Conditions	Yield
With 2,2,6,6-tetramethyl-piperidine; tributylstannyl trifluoromethanesulfonate In 1,2-dichloro-benzene at 20℃; for 2h; Inert atmosphere;	A 7% B 91%
With C56H65FeN2 In toluene at 20℃; for 7h; Catalytic behavior; Inert atmosphere; Glovebox; Schlenk technique;	A 10% B 90%
With [Mg{CH(SiMe3)2}(THF)2] In benzene-d6 at 60℃; Mechanism; Inert atmosphere;

dimethylamine borane (74-94-2) + tributylstannyl trifluoromethanesulfonate (68725-14-4) → (μ-dimethylamino)diborane (23273-02-1) + tri-n-butyl-tin hydride (688-73-3) + cyclic(dimethylamino borane) dimer (23884-11-9)

Conditions	Yield
With 2,2,6,6-tetramethylpiperidine In further solvent(s) byproducts: H2; N2 or Ar; 1,2-dichlorobenzene soln. of nBuSnOTf (0.39 mmol) and 2,2,6,6-tetramethylpiperidine (0.4 mmol) added to soln. of B compd. (0.42 mmol), mixt. stirred at 20°c for 2 h; NMR;	A 2% B n/a C 91%

1,3,5-Trioxan (110-88-3) + n-butyllithium (109-72-8, 29786-93-4) + dimethylamine borane (74-94-2) → lithium (dimethylamino)hydroborate, adduct with 1,3,5-trioxane

Conditions	Yield
In hexane; toluene byproducts: butane; (anhydrous conditions); dissoln. of BH3*NHMe2 and 1,3,5-trioxane in toluene, addn. of n-BuLi in hexane within 10 min with stirring, reflux (1 h); filtration while hot, crystn. on cooling, recrystn. (hot toluene); elem.anal.;	90%

n-butyllithium (109-72-8, 29786-93-4) + N,N,N,N,-tetramethylethylenediamine (110-18-9) + dimethylamine borane (74-94-2) → lithium (dimethylamino)hydroborate, adduct with N,N,N',N'-tetramethylethylenediamine

Conditions	Yield
In hexane byproducts: butane; (anhydrous conditions); dissoln. of BH3*NHMe2 in TMEDA, after cooling inan ice-bath addn. of n-BuLi in hexane within 1 h with stirring, further stirring at room temp. for 2 h; addn. of hexane, filtration, crystn. within 12 h and additionally by cooling of the supernatant to -18°C; elem. anal.;	90%

n-butyllithium (109-72-8, 29786-93-4) + (1,4,7,10-tetraoxacyclododecane) (294-93-9) + dimethylamine borane (74-94-2) → lithium (dimethylamino)hydroborate, adduct with 12-crown-4

Conditions	Yield
In hexane; toluene byproducts: butane; (anhydrous conditions); dissoln. of BH3*NHMe2 and 12-crown-4 in toluene,addn. of n-BuLi in hexane within 10 min with stirring, reflux (1 h); filtration while hot, crystn. on cooling; elem. anal.;	90%

dimethylamine borane (74-94-2) → (μ-dimethylamino)diborane (23273-02-1) + cyclic(dimethylamino borane) dimer (23884-11-9)

Conditions	Yield
With 2,2,6,6-tetramethylpiperidine; Me3SiOTf In further solvent(s) byproducts: H2; N2 or Ar; 1,2-dichlorobenzene soln. of Me3SiOTf (0.39 mmol) and 2,2,6,6-tetramethylpiperidine (0.4 mmol) added to soln. of B compd. (0.42 mmol), mixt. stirred at 20°c for 2 h; NMR;	A 3% B 89%
With 2,2,6,6-tetramethylpiperidine; Et3SiOTf In further solvent(s) byproducts: H2; N2 or Ar; 1,2-dichlorobenzene soln. of Et3SiOTf (0.39 mmol) and 2,2,6,6-tetramethylpiperidine (0.4 mmol) added to soln. of B compd. (0.42 mmol), mixt. stirred at 20°c for 2 h; NMR;	A 1% B 87%
With 2,6-di-tert-burtylpyridine; Me3SiOTf In further solvent(s) byproducts: H2; N2 or Ar; 1,2-dichlorobenzene soln. of Me3SiOTf (0.39 mmol) and 2,6-di-tert-butylpyridine (0.4 mmol) added to soln. of B compd. (0.42 mmol), mixt. stirred at 20°c for 2 h; NMR;	A 18% B 31%

tris(pentafluorophenyl)alane toluene + dimethylamine borane (74-94-2) → C20H10AlBF15N

Conditions	Yield
In toluene for 0.0833333h; Inert atmosphere; Schlenk technique;	87%

hydrogenchloride (7647-01-0) + dimethylamine borane (74-94-2) → N-Dimethyl-B-monochlor-borazan

Conditions	Yield
In tetrahydrofuran; diethyl ether Inert atmosphere; Schlenk technique; Glovebox;	86%
with stoichiometric amounts;;
with stoichiometric amounts;;

dimethylamine borane (74-94-2) + C33H51CaN3O → C35H61BCaN4O

Conditions	Yield
In toluene at 20℃; for 0.5h; Inert atmosphere;	86%

dimethylamine borane (74-94-2) + oxalic acid (144-62-7) → C2H7N*C4BO8(1-)*H(1+)

Conditions	Yield
In tetrahydrofuran at 20℃; for 64h; Inert atmosphere;	85%

dimethylamine borane (74-94-2) + potassium hydride → potassium dimethylaminoborohydride

Conditions	Yield
In tetrahydrofuran at 20℃; for 3 - 5h; Inert atmosphere;	83%

dimethylamine borane (74-94-2) → {(CH3)2NBH2}2

Conditions	Yield
With C52H46BFeO2P4(1+)*Br(1-); potassium tert-butylate In toluene at 23℃; for 16h; Catalytic behavior;	83%

dimethylamine borane (74-94-2) + water-d2 (7789-20-0) → BH3*NDMe2 (65761-09-3)

Conditions	Yield
In D2O (Ar); a soln. of B compd. stirred at 40°C for 24 h; extd. (CH2Cl2), the org. layer dried (MgSO4), filtered, evapd., sublimedtwice under dynamic vac. at 20°C;	82%

Upstream product

• 124-40-3 dimethyl amine 
• 1333-74-0 hydrogen 
• 7732-18-5 water 
• 19287-45-7 diborane 
• 19121-56-3 phosphine-borane 
• 75-22-9 trimethylamine-borane 
• 14931-39-6 P(BH₃)F₃ 
• 1722-26-5 triethylamine-borane 
• 506-59-2 N,N-dimethylammonium chloride 
• 99572-50-6 (t-C₄H₉SBH₂)3 
• 1838-13-7 dimethylamine borane 
• 272443-95-5 N,N',N''-triisopropylborazane 
• 26200-46-4 N,N',N''-tripropylborazane 
• 26200-45-3 N,N',N''-triethylborazane 

Downstream Products

• 7440-57-5 gold 
• 10043-11-5 boron nitride 
• 1333-74-0 hydrogen 
• 506-59-2 N,N-dimethylammonium chloride 
• 11113-50-1 boric acid 
• 55124-38-4 Dimethylaminohydridophenoxyboran 
• 1838-13-7 dimethylamine borane 
• 23273-02-1 (μ-dimethylamino)diborane 
• 13072-44-1 (CH₃)2HNBCl₃ 
• 4375-83-1 tris(dimethylamino)borane 
• 7289-86-3 Dimethylamino-di-n-butyl-boran 
• 15243-31-9 Li{B(n-C₄H₉)4} 
• 1073349-16-2 [Rh(H)2(P(i-Bu)3)2(η2-H3B*NHMe2)][B(3,5-C6H3(CF3)2)4] 
• 23884-11-9 cyclic(dimethylamino borane) dimer 

Relevant articles and documents

H/D scrambling in a chromium-catalyzed dehydrocoupling reaction of a borane-dimethylamine adduct

H/D scrambling took place in a chromium-catalyzed dehydrocoupling reaction of a deuterium-labeled borane-dimethylamine adduct. In the hydrogen elimination of BH3·NDMe2 (1a-dN), H2, HD and D2 were generated in 65:30:5 ratio, and 62% of deuterium atoms were incorporated into the major product, the dimethylaminoborane dimer. Proton and deuteron nuclei were thus concentrated into the evolved dihydrogen and aminoborane dimer, respectively. The mechanism of H/D scrambling is understood based on the reaction pathway of the dehydrocoupling of 1a, which was previously proposed based on DFT calculations. The H/D distribution in the products is explained by the energy difference according to the deuterated position in an intermediate of the dehydrocoupling reaction.

Preparation and basicity of sodium dimethylamidotrihydroborate(III)

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Preparation method of dimethylamine borane

The invention discloses a preparation method of dimethylamine borane, which comprises the following step of in a solvent, in the presence of monopotassium phosphate or phosphoric acid, reacting dimethylamine or hydrochloride thereof with BH4 ion-containing hydroboron to obtain the dimethylamine borane. The solvent is water or a mixed solvent of water and an organic solvent. The preparation method of dimethylamine borane disclosed by the invention is mild in condition, high in yield, high in purity and clean in reaction.

Method for the production of amine borane complex (by machine translation)

The invention belongs to the technical field of material preparation, in particular relates to a method for the production of amine borane complex. This invention adopts the borane amine of the direct reaction of an inert gas stream, by regulating the ratio of the two, the need for further post-processing, to make the final product amine complex and offer. In the reaction process such impurity is introduced into the salt-free, does not use an organic solvent; the use of borohydride such as the reagent to produce the borane, for now the current system, can avoid direct operation of toxic gas borane. The method of the invention is simple in operation, the product has high purity, low cost, and can be continuous large-scale production. At the same time, the method and other way to produce the amine borane complex equipment compatible, production equipment by simple method can be used to adjust the production. (by machine translation)