methyl 5-O-[2,3-di-O-benzoyl-α-D-arabinofuranosyl]-2,3-anhydro-α-D-lyxofuranoside

Base Information

Chemical Name:methyl 5-O-[2,3-di-O-benzoyl-α-D-arabinofuranosyl]-2,3-anhydro-α-D-lyxofuranoside
CAS No.:352438-51-8
Molecular Formula:C₂₅H₂₆O₁₀
Molecular Weight:486.475
Hs Code.:

Synonyms:methyl 5-O-[2,3-di-O-benzoyl-α-D-arabinofuranosyl]-2,3-anhydro-α-D-lyxofuranoside

Suppliers and Price of methyl 5-O-[2,3-di-O-benzoyl-α-D-arabinofuranosyl]-2,3-anhydro-α-D-lyxofuranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 5-O-[2,3-di-O-benzoyl-α-D-arabinofuranosyl]-2,3-anhydro-α-D-lyxofuranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 5-O-[2,3-di-O-benzoyl-α-D-arabinofuranosyl]-2,3-anhydro-α-D-lyxofuranoside

There total 5 articles about methyl 5-O-[2,3-di-O-benzoyl-α-D-arabinofuranosyl]-2,3-anhydro-α-D-lyxofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 352438-50-7
methyl 5-O-[5-O-tert-butyldiphenylsilyl-2,3-di-O-benzoyl-α-D-arabinofuranosyl]-2,3-anhydro-α-D-lyxofuranoside

: 352438-51-8
methyl 5-O-[2,3-di-O-benzoyl-α-D-arabinofuranosyl]-2,3-anhydro-α-D-lyxofuranoside

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 0 ℃; for 1h;
DOI:10.1021/jo001747a

Reference yield:

: 98-88-4
benzoyl chloride

: 352438-51-8
methyl 5-O-[2,3-di-O-benzoyl-α-D-arabinofuranosyl]-2,3-anhydro-α-D-lyxofuranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 2.52 g / pyridine / 0 - 20 °C

2: 84 percent / Ni-iodosuccinimide; silver triflate / CH₂Cl₂ / 0.25 h / 0 °C

3: 81 percent / TBAF / tetrahydrofuran / 1 h / 0 °C

With pyridine; N-iodo-succinimide; tetrabutyl ammonium fluoride; silver trifluoromethanesulfonate; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo001747a

Reference yield:

: 204918-49-0
p-methylphenyl 1-thio-α-D-arabinofuranoside

: 352438-51-8
methyl 5-O-[2,3-di-O-benzoyl-α-D-arabinofuranosyl]-2,3-anhydro-α-D-lyxofuranoside

Guidance literature:: Multi-step reaction with 4 steps

1: pyridine / 5 h / 0 - 20 °C

2: 2.52 g / pyridine / 0 - 20 °C

3: 84 percent / Ni-iodosuccinimide; silver triflate / CH₂Cl₂ / 0.25 h / 0 °C

4: 81 percent / TBAF / tetrahydrofuran / 1 h / 0 °C

With pyridine; N-iodo-succinimide; tetrabutyl ammonium fluoride; silver trifluoromethanesulfonate; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo001747a