YbCl₂(N(C₆H₃(CH(CH₃)2)2)Si(CH₃)3)(OC₄H₈)3

Base Information

• Chemical Name: YbCl₂(N(C₆H₃(CH(CH₃)2)2)Si(CH₃)3)(OC₄H₈)3
• CAS No.: 945487-28-5
• Molecular Formula: C₂₇H₅₀Cl₂NO₃SiYb
• Molecular Weight: 708.73
• Mol file: 945487-28-5.mol

Synonyms:YbCl₂(N(C₆H₃(CH(CH₃)2)2)Si(CH₃)3)(OC₄H₈)3

Chemical Property of YbCl₂(N(C₆H₃(CH(CH₃)2)2)Si(CH₃)3)(OC₄H₈)3

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of YbCl₂(N(C₆H₃(CH(CH₃)2)2)Si(CH₃)3)(OC₄H₈)3

There total 1 articles about YbCl₂(N(C₆H₃(CH(CH₃)2)2)Si(CH₃)3)(OC₄H₈)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + ytterbium(III) chloride (10361-91-8) + lithium (2,6-diisopropylphenyl)(trimethylsilyl)amide (134208-71-2) → YbCl2(N(C6H3(CH(CH3)2)2)Si(CH3)3)(OC4H8)3 (945487-28-5)

Guidance literature:

In tetrahydrofuran; hexane; byproducts: LiCl; under Ar; Li compd. in hexane added slowly to slurry of YbCl3 (molar ratio 1:1) in THF; stirred at room temp. for 48 h; solvent removed under vac.; extd. with toluene; centrifuged; concd.; crystd. at room temp. for a few d; elem. anal.;

DOI:10.1021/ic070162x

Reference yield: 75.0%

YbCl2(N(C6H3(CH(CH3)2)2)Si(CH3)3)(OC4H8)3 (945487-28-5) → (YbCl(N(C6H3(CH(CH3)2)2)Si(CH3)3)(OC4H8)2)2

Guidance literature:

With Na-K alloy; In tetrahydrofuran; toluene; under Ar; Na-K alloy in toluene added to soln. of Yb complex in THF; stirred at 40°C for 72 h; centrifuged; solvent removed; extd. with toluene; centrifuged; crystd. at room temp.;

DOI:10.1021/ic070162x

upstream raw materials:

tetrahydrofuran

ytterbium(III) chloride

lithium (2,6-diisopropylphenyl)(trimethylsilyl)amide