Ytterbium chloride (YbCl3)

Base Information

• Chemical Name: Ytterbium chloride (YbCl3)
• CAS No.: 10361-91-8
• Molecular Formula: Cl3Yb
• Molecular Weight: 279.399
• Wikidata: Q415548
• Mol file: 10361-91-8.mol

Synonyms:ytterbium chloride;ytterbium trichloride;ytterbium trichloride, (169)Yb-labeled

Chemical Property of Ytterbium chloride (YbCl3)

Chemical Property:

• Vapor Pressure: 33900mmHg at 25°C
• Melting Point: 854oC
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 2.06850
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 278.845426
• Heavy Atom Count: 4
• Complexity: 8

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Rare Earth Metals
• Canonical SMILES: Cl[Yb](Cl)Cl

Technology Process of Ytterbium chloride (YbCl3)

There total 29 articles about Ytterbium chloride (YbCl3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

ytterbium bis(tert-butoxide) → ytterbium(III) chloride (10361-91-8)

Guidance literature:

With hydrogenchloride; In toluene; condensing gaseous HCl with liquid nitrogen in an ampul containing toluene solution of (((CH3)3CO)2Yb; warming to room temperature;

Reference yield: 100.0%

bis(bis(trimethylsilyl)amino)ytterbium * 1,2-dimethoxyethane (90669-97-9) → chloro-trimethyl-silane (75-77-4) + 1,2-dimethoxyethane (110-71-4) + ytterbium(III) chloride (10361-91-8) + ammonium chloride

Guidance literature:

With hydrogenchloride; In toluene; condensing gaseous HCl with liquid nitrogen in an ampul containing toluene solution of (((CH3)3Si)2N)2Yb*CH3O(CH2)2OCH3; warming to room temperature; removing volatile compounds ((CH3)3SiCl, DME) by vac. condensation; vac. sublimation at 100°C (1E-2 mm): NH4Cl;;

Reference yield: 99.0%

(C6H5)2(C4H8O)Yb(C6H5)3Yb(C4H8O)3 → ytterbium(III) chloride (10361-91-8)

Guidance literature:

With HCl; In toluene; byproducts: C6H6; condensing of gaseous HCl into a suspn. of the starting complex in toluene, heating for 1.5 h in a boiling water bath, all manipulations under vac.; removal of the volatiles and solvent in vac.;

DOI:10.1016/0022-328X(92)83316-A

upstream raw materials:

hydrogenchloride

ytterbium trichloride hydrate

YbCl₃*3H₂O

tertiary butyl chloride

Downstream raw materials:

(YbCl₃((C₆H₁₁)2PHO)3)

ytterbium nitride

Refernces

• 1、 Danilov,Krylov,Korpusov,Kostikova,Barabanov,Bezrukov,Kornoukhov,Nesterova,Yanovich,Yakshin,Tsarenko,Cattadori,Ferrari,Falgiani. "Scintillators based on ytterbium chloride adducts with neutral organophosphorus extractants for detecting solar neutrino for LENS (Low-Energy Neutrino Spectroscopy) experiment". . p. 140 - 145. Retrieved 2003.
• 2、 Meshkova,Topilova,Devyatykh,Gusev,Shul'Gin. "IR luminescence of neodymium(III) and ytterbium(III) ions in complexes with N-alkyl-substituted 2-aminobenzoic acids". . p. 262 - 266. Retrieved 2011.
• 3、 Parvulescu, V. I.,Vasiliu, F.,Segal, E.. "". . p. 1313 - 1322. Retrieved 1995.
• 4、 Novoselova,Smolenskii. "Redox reaction Yb(III) + e = Yb(II) in a molten eutectic mixture NaCl-2CsCl". . p. 2133 - 2138. Retrieved 2009.
• 5、 Lasocha,Voos-Esquivel,Hodorowicz,Kim,Eick. "X-RAY POWDER DIFFRACTION STUDY OF THE YbCl2-Ybl2 SYSTEM.". . p. 67 - 73. Retrieved 1988.
• 6、 Janicki, Rafal,Starynowicz, Przemyslaw,Mondry, Anna. "Lanthanide carbonates". . p. 3601 - 3616. Retrieved 2011/10/11.