Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-3-(2-oxopropyl)-, (1R,3R,4R)- (9CI)

Base Information

Chemical Name:Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-3-(2-oxopropyl)-, (1R,3R,4R)- (9CI)
CAS No.:777882-71-0
Molecular Formula:C₁₈H₂₂O₂
Molecular Weight:270.371
Hs Code.:
Mol file:777882-71-0.mol

Synonyms:Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-3-(2-oxopropyl)-, (1R,3R,4R)- (9CI)

Suppliers and Price of Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-3-(2-oxopropyl)-, (1R,3R,4R)- (9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-3-(2-oxopropyl)-, (1R,3R,4R)- (9CI)

Chemical Property:

PSA：34.14000
LogP:2.60690

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-3-(2-oxopropyl)-, (1R,3R,4R)- (9CI)

There total 6 articles about Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-3-(2-oxopropyl)-, (1R,3R,4R)- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 10293-06-8
(1R)-3-endo-bromocamphor

: 78386-38-6
1-tert-butoxy-1-phenylethene

: 777882-71-0
(1R,3R,4R)-1,7,7-Trimethyl-3-(2-oxo-2-phenyl-ethyl)-bicyclo[2.2.1]heptan-2-one

: 777882-71-0
(1R,3S,4R)-1,7,7-Trimethyl-3-(2-oxo-2-phenyl-ethyl)-bicyclo[2.2.1]heptan-2-one

Guidance literature:: With 2,4,6-trimethyl-pyridine; 2,2'-azobis(isobutyronitrile); In benzene; at 85 ℃; for 3h; Title compound not separated from byproducts;
DOI:10.1039/b407215b

Reference yield:

: 10293-06-8
(1R)-3-endo-bromocamphor

: 78386-38-6
1-tert-butoxy-1-phenylethene

: 777882-71-0
(1R,3R,4R)-1,7,7-Trimethyl-3-(2-oxo-2-phenyl-ethyl)-bicyclo[2.2.1]heptan-2-one

: 777882-71-0
(1R,3S,4R)-1,7,7-Trimethyl-3-(2-oxo-2-phenyl-ethyl)-bicyclo[2.2.1]heptan-2-one

Guidance literature:: With 2,4,6-trimethyl-pyridine; 2,2'-azobis(isobutyronitrile); In benzene; at 85 ℃; for 3h; Title compound not separated from byproducts;
DOI:10.1039/b407215b

Reference yield:

: 100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6
styrene

: 777882-71-0
(1R,3R,4R)-1,7,7-Trimethyl-3-(2-oxo-2-phenyl-ethyl)-bicyclo[2.2.1]heptan-2-one

Guidance literature:: Multi-step reaction with 2 steps

1.1: iodine; mercuric oxide / diethyl ether / 3 h / 20 °C

1.2: 76 percent / t-BuOK / diethyl ether; tetrahydrofuran / 20 °C

2.1: AIBN; 2,4,6-collidine / benzene / 3 h / 85 °C

With 2,4,6-trimethyl-pyridine; 2,2'-azobis(isobutyronitrile); iodine; mercury(II) oxide; In diethyl ether; benzene;
DOI:10.1039/b407215b