benzyl α-allyldiazoacetate

Base Information

Chemical Name:benzyl α-allyldiazoacetate
CAS No.:1231734-95-4
Molecular Formula:C₁₂H₁₂N₂O₂
Molecular Weight:216.239
Hs Code.:

Synonyms:benzyl α-allyldiazoacetate

Suppliers and Price of benzyl α-allyldiazoacetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of benzyl α-allyldiazoacetate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of benzyl α-allyldiazoacetate

There total 2 articles about benzyl α-allyldiazoacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 123326-15-8
(rac)-benzyl 2-acetylpent-4-enoate

: 1231734-95-4
benzyl α-allyldiazoacetate

Guidance literature:: With 4-acetamidobenzenesulfonyl azide; 1,8-diazabicyclo[5.4.0]undec-7-ene; In acetonitrile; at 0 - 20 ℃;
DOI:10.1021/ja102832f

Reference yield:

: 5396-89-4
benzyl acetoacetate

: 1231734-95-4
benzyl α-allyldiazoacetate

Guidance literature:: Multi-step reaction with 2 steps

1: sodium hydride / tetrahydrofuran; mineral oil / 0 °C / Reflux; Inert atmosphere

2: 4-acetamidobenzenesulfonyl azide; 1,8-diazabicyclo[5.4.0]undec-7-ene / acetonitrile / 24 h / 0 - 20 °C / Inert atmosphere

With 4-acetamidobenzenesulfonyl azide; sodium hydride; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; acetonitrile; mineral oil;
DOI:10.1002/anie.201204350

Reference yield: 96.0%

: 1231734-95-4
benzyl α-allyldiazoacetate

: 100-52-7
benzaldehyde

: benzyl 2-benzoylpent-4-enoate

Guidance literature:: With C₄₃H₆₄N₄O₄; scandium tris(trifluoromethanesulfonate); In dichloromethane; at -20 ℃; for 2h; optical yield given as %ee; enantioselective reaction; Inert atmosphere; Molecular sieve;
DOI:10.1021/ja102832f