(3S,5S,6S)-3-[(1S,3R)-1-hydroxy-3-methyl-4-(5-nitro-2,3,6-trimethoxy-phenyl)-butyl]-5,6-bis-(4-methoxy-phenyl)-[1,4]dioxan-2-one

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Chemical Name:(3S,5S,6S)-3-[(1S,3R)-1-hydroxy-3-methyl-4-(5-nitro-2,3,6-trimethoxy-phenyl)-butyl]-5,6-bis-(4-methoxy-phenyl)-[1,4]dioxan-2-one
CAS No.:326606-16-0
Molecular Formula:C₃₂H₃₇NO₁₁
Molecular Weight:611.646
Hs Code.:

Synonyms:(3S,5S,6S)-3-[(1S,3R)-1-hydroxy-3-methyl-4-(5-nitro-2,3,6-trimethoxy-phenyl)-butyl]-5,6-bis-(4-methoxy-phenyl)-[1,4]dioxan-2-one

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Chemical Property of (3S,5S,6S)-3-[(1S,3R)-1-hydroxy-3-methyl-4-(5-nitro-2,3,6-trimethoxy-phenyl)-butyl]-5,6-bis-(4-methoxy-phenyl)-[1,4]dioxan-2-one

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Technology Process of (3S,5S,6S)-3-[(1S,3R)-1-hydroxy-3-methyl-4-(5-nitro-2,3,6-trimethoxy-phenyl)-butyl]-5,6-bis-(4-methoxy-phenyl)-[1,4]dioxan-2-one

There total 15 articles about (3S,5S,6S)-3-[(1S,3R)-1-hydroxy-3-methyl-4-(5-nitro-2,3,6-trimethoxy-phenyl)-butyl]-5,6-bis-(4-methoxy-phenyl)-[1,4]dioxan-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 326606-10-4
(3R)-3-methyl-4-(5-nitro-2,3,6-trimethoxyphenyl)-butyraldehyde

: 326606-11-5
(S,S)-5,6-bis-(4-methoxyphenyl)-[1,4]-dioxan-2-one

: 326606-16-0
(3S,5S,6S)-3-[(1S,3R)-1-hydroxy-3-methyl-4-(5-nitro-2,3,6-trimethoxy-phenyl)-butyl]-5,6-bis-(4-methoxy-phenyl)-[1,4]dioxan-2-one

Guidance literature:: With tert-butyldimethylsilyl chloride; 2,2'-iminobis[ethanol]; magnesium bromide; In ethyl acetate; at 20 ℃; for 18h; Reagent/catalyst;

Reference yield: 70.0%

: 326606-10-4
(3R)-3-methyl-4-(5-nitro-2,3,6-trimethoxyphenyl)-butyraldehyde

: 326606-11-5
(S,S)-5,6-bis-(4-methoxyphenyl)-[1,4]-dioxan-2-one

: (3S,5S,6S)-3-[(1R,3R)-1-hydroxy-3-methyl-4-(5-nitro-2,3,6-trimethoxy-phenyl)-butyl]-5,6-bis-(4-methoxy-phenyl)-[1,4]dioxan-2-one

: 326606-16-0
(3S,5S,6S)-3-[(1S,3R)-1-hydroxy-3-methyl-4-(5-nitro-2,3,6-trimethoxy-phenyl)-butyl]-5,6-bis-(4-methoxy-phenyl)-[1,4]dioxan-2-one

Guidance literature:: (S,S)-5,6-bis-(4-methoxyphenyl)-[1,4]-dioxan-2-one; With triethylamine; dicyclohexyl(((trifluoromethyl)sulfonyl)oxy)borane; In hexane; dichloromethane; at -78 ℃;

(3R)-3-methyl-4-(5-nitro-2,3,6-trimethoxyphenyl)-butyraldehyde; In hexane; dichloromethane; at -78 ℃; for 3h;
DOI:10.1021/ol0068997

Reference yield: 70.0%

: 326606-10-4
(3R)-3-methyl-4-(5-nitro-2,3,6-trimethoxyphenyl)-butyraldehyde

: 326606-11-5
(S,S)-5,6-bis-(4-methoxyphenyl)-[1,4]-dioxan-2-one

: (3R,5S,6S)-3-[(1R,3R)-1-hydroxy-3-methyl-4-(5-nitro-2,3,6-trimethoxy-phenyl)-butyl]-5,6-bis-(4-methoxy-phenyl)-[1,4]dioxan-2-one

: 326606-16-0
(3S,5S,6S)-3-[(1S,3R)-1-hydroxy-3-methyl-4-(5-nitro-2,3,6-trimethoxy-phenyl)-butyl]-5,6-bis-(4-methoxy-phenyl)-[1,4]dioxan-2-one

Guidance literature:: (3R)-3-methyl-4-(5-nitro-2,3,6-trimethoxyphenyl)-butyraldehyde; With triethylamine; dicyclohexyl(((trifluoromethyl)sulfonyl)oxy)borane; In hexane; dichloromethane; at -78 ℃; for 3h;

(S,S)-5,6-bis-(4-methoxyphenyl)-[1,4]-dioxan-2-one; In hexane; dichloromethane; at -78 ℃; for 3h;

With dihydrogen peroxide; In various solvents; at -78 - 20 ℃; pH=7; Further stages.;
DOI:10.1021/ol0267432