O-ethyl S-2-(4-methoxyphenyl)-2-oxoethyl carbonodithioate

Base Information

• Chemical Name: O-ethyl S-2-(4-methoxyphenyl)-2-oxoethyl carbonodithioate
• CAS No.: 93624-01-2
• Molecular Formula: C₁₂H₁₄O₃S₂
• Molecular Weight: 270.373
• Mol file: 93624-01-2.mol

Synonyms:O-ethyl S-2-(4-methoxyphenyl)-2-oxoethyl carbonodithioate

Chemical Property of O-ethyl S-2-(4-methoxyphenyl)-2-oxoethyl carbonodithioate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of O-ethyl S-2-(4-methoxyphenyl)-2-oxoethyl carbonodithioate

There total 6 articles about O-ethyl S-2-(4-methoxyphenyl)-2-oxoethyl carbonodithioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

potassium ethyl xanthogenate (140-89-6) + 2-Bromo-4'-methoxyacetophenone (2632-13-5) → O-ethyl S-2-(4-methoxyphenyl)-2-oxoethyl carbonodithioate (93624-01-2)

Guidance literature:

2-Bromo-4'-methoxyacetophenone; With sodium iodide; In acetone; at 20 ℃; for 0.166667h;

potassium ethyl xanthogenate; In acetone; at 20 ℃; for 0.333333h;

DOI:10.1039/c9ob00701f

Reference yield: 95.0%

2-diazo-1-(4-methoxyphenyl)ethanone (6832-17-3) + potassium ethyl xanthogenate (140-89-6) → O-ethyl S-2-(4-methoxyphenyl)-2-oxoethyl carbonodithioate (93624-01-2)

Guidance literature:

2-diazo-1-(4-methoxyphenyl)ethanone; With toluene-4-sulfonic acid; In dichloromethane; at 20 ℃;

potassium ethyl xanthogenate; In dichloromethane; at 20 ℃; for 4h; Solvent; Reagent/catalyst;

DOI:10.1055/a-1513-9968

Reference yield: 52.0%

diazomethane (186581-53-3,908094-01-9,334-88-3) + potassium ethyl xanthogenate (140-89-6) + 4-methoxybenzoic acid (100-09-4) → O-ethyl S-2-(4-methoxyphenyl)-2-oxoethyl carbonodithioate (93624-01-2)

Guidance literature:

4-methoxybenzoic acid; With N-Bromosuccinimide; triphenylphosphine; In tetrahydrofuran; dichloromethane; at 0 ℃; for 0.166667h; Inert atmosphere;

diazomethane; In tetrahydrofuran; diethyl ether; dichloromethane; at 20 ℃; for 16h;

potassium ethyl xanthogenate; With toluene-4-sulfonic acid; In tetrahydrofuran; diethyl ether; dichloromethane; at 20 ℃; for 4h;

DOI:10.1055/a-1513-9968

upstream raw materials:

potassium ethyl xanthogenate

2-Bromo-4'-methoxyacetophenone

sodium O-ethyl dithiocarbonate

2-diazo-1-(4-methoxyphenyl)ethanone

Downstream raw materials:

4-(4-Methoxybenzoyl)-5-methylthio-1,3-dithiol-2-thion

dithiocarbonic acid S-[1-(1,3-dioxo-1,3-dihydro-isoindol-2-ylmethyl)-4-(4-methoxy-phenyl)-4-oxo-butyl] ester O-ethyl ester

dithiocarbonic acid S-[1-(1-tert-butoxycarbonylamino-1-methyl-ethyl)-4-(4-methoxy-phenyl)-4-oxo-butyl] ester O-ethyl ester

dithiocarbonic acid O-ethyl ester S-{1-[3-(4-methoxy-phenyl)-3-oxo-propyl]-heptyl} ester