(η(6)-C6Me6)RuCl2(dimethylphenylphosphine)

Base Information

Chemical Name:(η(6)-C6Me6)RuCl2(dimethylphenylphosphine)
CAS No.:110800-51-6
Molecular Formula:C₂₀H₂₉Cl₂PRu
Molecular Weight:472.4
Hs Code.:

Synonyms:(η(6)-C6Me6)RuCl2(dimethylphenylphosphine)

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Chemical Property of (η(6)-C6Me6)RuCl2(dimethylphenylphosphine)

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Technology Process of (η(6)-C6Me6)RuCl2(dimethylphenylphosphine)

There total 1 articles about (η(6)-C6Me6)RuCl2(dimethylphenylphosphine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: [RuCl₂(hexamethylbenzene)]2

: 672-66-2
Dimethyl(phenyl)phosphine

: 110800-51-6
(η(6)-C6Me6)RuCl2(dimethylphenylphosphine)

Guidance literature:: In chloroform; inert atmosphere; refluxing Ru-complex with excess phosphine for 6 h; concn., pptn. on hexane addn., washing (hexane), drying (vac.); elem. anal.;
DOI:10.1016/S0022-328X(96)06568-0

Reference yield: 60.0%

: 110800-51-6
(η(6)-C6Me6)RuCl2(dimethylphenylphosphine)

: 13170-43-9
(trimethylsilyl)methylmagnesium chloride

: {Ru(CH2SiMe3)(η6-C6Me6)(PMe2Ph)}

Guidance literature:: In diethyl ether; under N2 or Ar, addn. of dioxane, stirring; solvent pump off, addn. to pentane, hydrolyzing at 0°C with H2O, drying over Na2SO4, cooling to -20°C;
DOI:10.1039/DT9900001779

Reference yield: 59.0%

: sodium hexaflorophosphate

: 110800-51-6
(η(6)-C6Me6)RuCl2(dimethylphenylphosphine)

: 536-74-3
phenylacetylene

: {Ru(C₆(CH₃)6)(P(CH₃)2(C₆H₅))Cl(C(O(CH₃))CH₂C₆H₅)}⁽¹⁺⁾*PF₆^(1-) = {Ru(C₆(CH₃)6)(P(CH₃)2(C₆H₅))Cl(C(O(CH₃))CH₂C₆H₅)}PF₆

Guidance literature:: In methanol; (Ar) or (N2), stirred for 10-30 min at room temp.; added ether, precipitated, dissolved in CH2Cl2, filtered, added ether or hexane, cooled to -20°C; elem. anal., IR, NMR;
DOI:10.1021/om00054a045