(3S,3aS,5S,6S,7aS)-6-Benzyloxy-5-iodomethyl-3-methyl-hexahydro-furo[3,2-b]pyran-2-one

Base Information

Chemical Name:(3S,3aS,5S,6S,7aS)-6-Benzyloxy-5-iodomethyl-3-methyl-hexahydro-furo[3,2-b]pyran-2-one
CAS No.:78686-53-0
Molecular Formula:C₁₆H₁₉IO₄
Molecular Weight:402.229
Hs Code.:

Synonyms:(3S,3aS,5S,6S,7aS)-6-Benzyloxy-5-iodomethyl-3-methyl-hexahydro-furo[3,2-b]pyran-2-one

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Chemical Property of (3S,3aS,5S,6S,7aS)-6-Benzyloxy-5-iodomethyl-3-methyl-hexahydro-furo[3,2-b]pyran-2-one

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Technology Process of (3S,3aS,5S,6S,7aS)-6-Benzyloxy-5-iodomethyl-3-methyl-hexahydro-furo[3,2-b]pyran-2-one

There total 6 articles about (3S,3aS,5S,6S,7aS)-6-Benzyloxy-5-iodomethyl-3-methyl-hexahydro-furo[3,2-b]pyran-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 78686-52-9
Toluene-4-sulfonic acid (3S,3aS,5R,6S,7aS)-6-benzyloxy-3-methyl-2-oxo-hexahydro-furo[3,2-b]pyran-5-ylmethyl ester

: 78686-53-0
(3S,3aS,5S,6S,7aS)-6-Benzyloxy-5-iodomethyl-3-methyl-hexahydro-furo[3,2-b]pyran-2-one

Guidance literature:: With sodium iodide; In butanone; for 18h; Yield given; Heating;
DOI:10.1021/ja00401a047

Reference yield:

: 100-39-0
benzyl bromide

: 78686-53-0
(3S,3aS,5S,6S,7aS)-6-Benzyloxy-5-iodomethyl-3-methyl-hexahydro-furo[3,2-b]pyran-2-one

Guidance literature:: Multi-step reaction with 5 steps

3: Bu₃SnH / ethanol / 12 h / Ambient temperature

4: pyridine / 20 h / 0 °C

5: NaI / butan-2-one / 18 h / Heating

With pyridine; tri-n-butyl-tin hydride; sodium iodide; In ethanol; butanone;
DOI:10.1021/ja00401a047

Reference yield:

: 78686-51-8
(3S,3aS,5R,6S,7aS)-6-Benzyloxy-5-hydroxymethyl-3-methyl-hexahydro-furo[3,2-b]pyran-2-one

: 78686-53-0
(3S,3aS,5S,6S,7aS)-6-Benzyloxy-5-iodomethyl-3-methyl-hexahydro-furo[3,2-b]pyran-2-one

Guidance literature:: Multi-step reaction with 2 steps

1: pyridine / 20 h / 0 °C

2: NaI / butan-2-one / 18 h / Heating

With pyridine; sodium iodide; In butanone;
DOI:10.1021/ja00401a047