[meso-tetraphenyl-2,3-dioxoporphyrinato]nickel^II

Base Information

• Chemical Name: [meso-tetraphenyl-2,3-dioxoporphyrinato]nickel^II
• CAS No.: 574735-10-7
• Molecular Formula: C₄₄H₂₆N₄NiO₂
• Molecular Weight: 701.406
• Mol file: 574735-10-7.mol

Synonyms:[meso-tetraphenyl-2,3-dioxoporphyrinato]nickel^II

Chemical Property of [meso-tetraphenyl-2,3-dioxoporphyrinato]nickel^II

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [meso-tetraphenyl-2,3-dioxoporphyrinato]nickel^II

There total 2 articles about [meso-tetraphenyl-2,3-dioxoporphyrinato]nickel^II which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

nickel(II) acetate tetrahydrate (6018-89-9) + 17,18-dioxo-5,10,15,20-tetraphenylchlorin → [meso-tetraphenyl-2,3-dioxoporphyrinato]nickelII (574735-10-7)

Guidance literature:

In benzonitrile; for 0.166667h; Reflux;

DOI:10.1002/ejoc.201300274

Reference yield: 70.0%

meso-tetraphenyl-2,3-dihydroxychlorin + nickel(II) acetate tetrahydrate (6018-89-9) → [meso-tetraphenyl-2,3-dioxoporphyrinato]nickelII (574735-10-7) + [meso-tetraphenyl-2,3-vic-diolchlorinato]nickel(II) + meso-tetraphenyl-2-oxa-3-oxoporphyrinatonickel(II) (922142-13-0) + (2-hydroxy-5,10,15,20-tetraphenylporphyrinato)nickel(II) (112803-38-0)

Guidance literature:

In pyridine; other Radiation; porphyrin, metal salt and pyridine were sealed in a glass tube, microwave power of 300 W, heated from room temp. to 180°C, stirred for 15min, cooled to 50°C; vessel was opened, decanted, TLC (silica gel), UV;

DOI:10.1039/b716181f

Reference yield: 92.0%

[meso-tetraphenyl-2,3-dioxoporphyrinato]nickelII (574735-10-7) → [meso-tetraphenyl-2,-hydroxyimino-3-oxoporphyrinato]nickel(II)

Guidance literature:

With hydroxylamine hydrochloride; In pyridine; at 20 ℃; for 24h; Inert atmosphere;

DOI:10.1021/jo502511j

upstream raw materials:

nickel(II) acetate tetrahydrate

Downstream raw materials:

Ni(Ph₄C₂₀H₆N₄O(N₂))

meso-tetraphenyl-2-oxa-3-oxoporphyrinatonickel(II)

(C₆H₅)4C₁₉H₆ON₄Ni

C₅₀H₄₀N₄NiO₅