3-(4-methanesulfonylphenoxy)-5-trifluoromethanesulfonyloxybenzoic acid methyl ester

Base Information

Chemical Name:3-(4-methanesulfonylphenoxy)-5-trifluoromethanesulfonyloxybenzoic acid methyl ester
CAS No.:1235567-12-0
Molecular Formula:C₁₆H₁₃F₃O₈S₂
Molecular Weight:454.402
Hs Code.:

Synonyms:3-(4-methanesulfonylphenoxy)-5-trifluoromethanesulfonyloxybenzoic acid methyl ester

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Chemical Property of 3-(4-methanesulfonylphenoxy)-5-trifluoromethanesulfonyloxybenzoic acid methyl ester

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Technology Process of 3-(4-methanesulfonylphenoxy)-5-trifluoromethanesulfonyloxybenzoic acid methyl ester

There total 2 articles about 3-(4-methanesulfonylphenoxy)-5-trifluoromethanesulfonyloxybenzoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 752242-45-8
3-hydroxy-5-(4-methanesulfonylphenoxy)benzoic acid methyl ester

: 358-23-6
trifluoromethylsulfonic anhydride

: 1235567-12-0
3-(4-methanesulfonylphenoxy)-5-trifluoromethanesulfonyloxybenzoic acid methyl ester

Guidance literature:: With triethylamine; In dichloromethane; at -78 ℃; for 2h;
DOI:10.1016/j.bmc.2014.02.009

Reference yield:

: 2150-44-9
1-carbomethoxy-3,5-dihydroxybenzene

: 1235567-12-0
3-(4-methanesulfonylphenoxy)-5-trifluoromethanesulfonyloxybenzoic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: caesium carbonate / N,N-dimethyl-formamide / 3 h / 180 °C

2: triethylamine / dichloromethane / 2 h / -78 °C

With caesium carbonate; triethylamine; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.bmc.2014.02.009

Reference yield: 91.0%

: 1235567-12-0
3-(4-methanesulfonylphenoxy)-5-trifluoromethanesulfonyloxybenzoic acid methyl ester

: 73183-34-3
bis(pinacol)diborane

: 1235567-13-1
3-(4-methanesulfonylphenoxy)-5-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)benzoic acid methyl ester

Guidance literature:: With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; In 1,4-dioxane; at 20 - 85 ℃; Inert atmosphere;
DOI:10.1016/j.bmc.2014.02.009