(3R,4R,5R,6R)-N-benzyloxycarbonyl-3-oxo-4,5,6-tribenzyloxyazepane

Base Information

Chemical Name:(3R,4R,5R,6R)-N-benzyloxycarbonyl-3-oxo-4,5,6-tribenzyloxyazepane
CAS No.:1357281-01-6
Molecular Formula:C₃₅H₃₅NO₆
Molecular Weight:565.666
Hs Code.:

Synonyms:(3R,4R,5R,6R)-N-benzyloxycarbonyl-3-oxo-4,5,6-tribenzyloxyazepane

Suppliers and Price of (3R,4R,5R,6R)-N-benzyloxycarbonyl-3-oxo-4,5,6-tribenzyloxyazepane

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Chemical Property of (3R,4R,5R,6R)-N-benzyloxycarbonyl-3-oxo-4,5,6-tribenzyloxyazepane

Chemical Property:

Purity/Quality:

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Technology Process of (3R,4R,5R,6R)-N-benzyloxycarbonyl-3-oxo-4,5,6-tribenzyloxyazepane

There total 10 articles about (3R,4R,5R,6R)-N-benzyloxycarbonyl-3-oxo-4,5,6-tribenzyloxyazepane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 1357280-99-9
(3R,4R,5R,6R)-N-benzyloxycarbonyl-3-hydroxy-4,5,6-tribenzyloxyazepane

: 1357281-01-6
(3R,4R,5R,6R)-N-benzyloxycarbonyl-3-oxo-4,5,6-tribenzyloxyazepane

Guidance literature:: With pyridinium chlorochromate; In dichloromethane; at 20 ℃; for 3h; Inert atmosphere; Molecular sieve;
DOI:10.1016/j.bmc.2010.09.053

Reference yield:

: 51103-66-3
methyl 6-O-(p-tolylsulfonyl)-α-D-mannopyranoside

: 1357281-01-6
(3R,4R,5R,6R)-N-benzyloxycarbonyl-3-oxo-4,5,6-tribenzyloxyazepane

Guidance literature:: Multi-step reaction with 8 steps

1: sodium azide / N,N-dimethyl-formamide

2: sodium hydride / N,N-dimethyl-formamide

3: sulfuric acid / dichloromethane / 0.08 h / -10 °C

4: sodium methylate / methanol / 1 h / 20 °C

5: triphenylphosphine / tetrahydrofuran

6: sodium cyanoborohydride; acetic acid

7: potassium hydrogencarbonate / water; ethyl acetate / 3 h / 0 °C

8: pyridinium chlorochromate / dichloromethane / 3 h / 20 °C / Inert atmosphere; Molecular sieve

With sodium azide; sulfuric acid; sodium methylate; sodium hydride; sodium cyanoborohydride; potassium hydrogencarbonate; acetic acid; triphenylphosphine; pyridinium chlorochromate; In tetrahydrofuran; methanol; dichloromethane; water; ethyl acetate; N,N-dimethyl-formamide;
DOI:10.1016/j.bmc.2010.09.053

Reference yield:

: 66224-56-4
methyl 6-azido-6-deoxy-α-D-mannopyranoside

: 1357281-01-6
(3R,4R,5R,6R)-N-benzyloxycarbonyl-3-oxo-4,5,6-tribenzyloxyazepane

Guidance literature:: Multi-step reaction with 7 steps

1: sodium hydride / N,N-dimethyl-formamide

2: sulfuric acid / dichloromethane / 0.08 h / -10 °C

3: sodium methylate / methanol / 1 h / 20 °C

4: triphenylphosphine / tetrahydrofuran

5: sodium cyanoborohydride; acetic acid

6: potassium hydrogencarbonate / water; ethyl acetate / 3 h / 0 °C

7: pyridinium chlorochromate / dichloromethane / 3 h / 20 °C / Inert atmosphere; Molecular sieve

With sulfuric acid; sodium methylate; sodium hydride; sodium cyanoborohydride; potassium hydrogencarbonate; acetic acid; triphenylphosphine; pyridinium chlorochromate; In tetrahydrofuran; methanol; dichloromethane; water; ethyl acetate; N,N-dimethyl-formamide;
DOI:10.1016/j.bmc.2010.09.053