(acetonitrile)pentacarbonylmanganese(I) tetrafluoroborate

Base Information

• Chemical Name: (acetonitrile)pentacarbonylmanganese(I) tetrafluoroborate
• CAS No.: 75008-28-5
• Molecular Formula: BF₄*C₇H₃MnNO₅
• Molecular Weight: 322.847
• Mol file: 75008-28-5.mol

Synonyms:(acetonitrile)pentacarbonylmanganese(I) tetrafluoroborate

Chemical Property of (acetonitrile)pentacarbonylmanganese(I) tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (acetonitrile)pentacarbonylmanganese(I) tetrafluoroborate

There total 1 articles about (acetonitrile)pentacarbonylmanganese(I) tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[bis(triphenylphospine)nitrogen(1+)][Re(CO)5] (119207-87-3) + {(CO)5Mn(η2-C2H4)BF4 (89253-25-8) → decacarbonyldirhenium(0) (14285-68-8) + dimanganese decacarbonyl (10170-69-1) + {(pentacarbonyl)rhenium(ethylene)}BF4 (78670-77-6) + (acetonitrile)pentacarbonylmanganese(I) tetrafluoroborate (75008-28-5) + [Mn2(CO)10(μ-C2H4)]

Guidance literature:

In acetonitrile; byproducts: [Re2(CO)10(μ-C2H4)], [(Ph3P)2N][Mn(CO)5]; (N2); glove-box, Schlenk-line technique; solids Re complex and Mn complex were mixed; CH3CN was added; not isolated; IR monitoring;

DOI:10.1016/S0020-1693(02)00793-4

Reference yield: 51.0%

(acetonitrile)pentacarbonylmanganese(I) tetrafluoroborate (75008-28-5) + trimethylamine oxide*2H2O + triphenylphosphine (603-35-0) + bis(triphenylphosphoranylidene)ammonium nitrite → Mn(CO)3(NO)(P(C6H5)3) (14695-07-9,22873-60-5)

Guidance literature:

In ethanol; N2 or Ar; soln. of (((C6H5)3P)2N)NO2 added dropwise to soln. of Mn(CO)5(CH3CN)BF4; soln. vac. distilled and condensed into another flask containing PPh3 at -196°C; warmed to room temp., soln. of MeNO*2H2O added dropwise with vigorous stirring; filtered; washed with cold ethanol; dried in vac.;

DOI:10.1016/S0020-1693(99)00546-0

Reference yield: 40.0%

(acetonitrile)pentacarbonylmanganese(I) tetrafluoroborate (75008-28-5) + dipotassium tricarbonylnitrosylmanganate + bis(triphenylphosphine)iminium chloride (21050-13-5) + bis(triphenylphosphoranylidene)ammonium nitrite → 2((C6H5)3P)2N(1+)*2Mn(2-)*6CO*2NO(1+) = [((C6H5)3P)2N]2[Mn2(CO)6(NO)2]

Guidance literature:

In tetrahydrofuran; byproducts: KCl; under N2 or Ar; freshly prepared soln. of Mn(CO)4(NO) from ((Ph3P)2N)NO2 and (Mn(CO)5(CH3CN))BF4 in THF added dropwise into slurry of K2(Mn(CO)3(NO)) in THF over 2 h; stirred overnight; filtered into a suspn. of ((C6H5)3P)2NCl; stirred for 16 h; filtered; THF removed in vac., about 20 ml; Et2O added; elem. anal.;

DOI:10.1016/S0020-1693(99)00546-0

upstream raw materials:

[bis(triphenylphospine)nitrogen⁽¹⁺⁾][Re(CO)5]

{(CO)5Mn(η2-C2H4)BF4

Downstream raw materials:

dimanganese decacarbonyl

bis(triphenylphosphineiminium) pentacarbonylmanganate^(1-)

pentacarbonyl(triphenylphosphine)manganese(I) cation

Mn(CO)3(NO)(P(C₆H₅)3)

Refernces