pentacarbonyl(triphenylphosphine)manganese(I) cation

Base Information

• Chemical Name: pentacarbonyl(triphenylphosphine)manganese(I) cation
• CAS No.: 54039-45-1
• Molecular Formula: C₂₃H₁₅MnO₅P
• Molecular Weight: 457.281
• Mol file: 54039-45-1.mol

Synonyms:pentacarbonyl(triphenylphosphine)manganese(I) cation

Chemical Property of pentacarbonyl(triphenylphosphine)manganese(I) cation

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of pentacarbonyl(triphenylphosphine)manganese(I) cation

There total 2 articles about pentacarbonyl(triphenylphosphine)manganese(I) cation which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hexacarbonylmanganese(I) tetrafluoroborate (15557-71-8) → pentacarbonyl(triphenylphosphine)manganese(I) cation (54039-45-1)

Guidance literature:

With triphenylphosphine; In acetic anhydride; byproducts: CO; with an excess of PPh3 at 35°C; detected by IR and GC; Kinetics;

DOI:10.1021/ja00539a008

Reference yield:

(acetonitrile)pentacarbonylmanganese(I) tetrafluoroborate (75008-28-5) → pentacarbonyl(triphenylphosphine)manganese(I) cation (54039-45-1)

Guidance literature:

With triphenylphosphine; In acetonitrile; detected by IR and GC; Kinetics;

DOI:10.1021/ja00539a008

Reference yield: 86.0%

pentacarbonyl(triphenylphosphine)manganese(I) cation (54039-45-1) + tetracarbonyl(triphenylphosphine)manganate (53418-18-1) → pentacarbonylmanganate (35816-56-9,14971-26-7,71564-22-2) + dimanganese octacarbonyl di-(triphenyl phosphine) (15279-67-1,10170-70-4)

Guidance literature:

With tetrabutylammonium perchlorate; In tetrahydrofuran; 5-mL aliquot of 1E-2 M Mn(CO)4PPh3(1-) in THF added under Ar to 5 mL of 1E-2 M Mn(CO)5PPh3(1+) in THF contg. 0.3 M TBAP at 22°C, react. complete within 5 min; not isolated; detected by IR;

DOI:10.1021/om00152a010

upstream raw materials:

hexacarbonylmanganese(I) tetrafluoroborate

(acetonitrile)pentacarbonylmanganese(I) tetrafluoroborate

Downstream raw materials:

dimanganese decacarbonyl

dimanganese octacarbonyl di-(triphenyl phosphine)

tetracarbonylhydrido(triphenylphosphine)manganese

Mn₂(CO)9(triphenylphosphine)