{[(1E,5E)-7-(tert-Butyl-dimethyl-silanyloxy)-1-isopropenyl-9-methyl-deca-1,5,7,8-tetraenyloxy]-dimethyl-silanyl}-benzene

Base Information

Chemical Name:{[(1E,5E)-7-(tert-Butyl-dimethyl-silanyloxy)-1-isopropenyl-9-methyl-deca-1,5,7,8-tetraenyloxy]-dimethyl-silanyl}-benzene
CAS No.:93782-80-0
Molecular Formula:C₂₈H₄₄O₂Si₂
Molecular Weight:468.827
Hs Code.:

Synonyms:{[(1E,5E)-7-(tert-Butyl-dimethyl-silanyloxy)-1-isopropenyl-9-methyl-deca-1,5,7,8-tetraenyloxy]-dimethyl-silanyl}-benzene

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Chemical Property of {[(1E,5E)-7-(tert-Butyl-dimethyl-silanyloxy)-1-isopropenyl-9-methyl-deca-1,5,7,8-tetraenyloxy]-dimethyl-silanyl}-benzene

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Technology Process of {[(1E,5E)-7-(tert-Butyl-dimethyl-silanyloxy)-1-isopropenyl-9-methyl-deca-1,5,7,8-tetraenyloxy]-dimethyl-silanyl}-benzene

There total 10 articles about {[(1E,5E)-7-(tert-Butyl-dimethyl-silanyloxy)-1-isopropenyl-9-methyl-deca-1,5,7,8-tetraenyloxy]-dimethyl-silanyl}-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 86486-68-2
1-(tert-butyldimethylsilyl)-2-chloro-3-methyl-2-buten-1-one

: 104376-44-5
(E)-1-iodo-7-methyl-6-(phenyldimethylsiloxy)-1,5,7-octatriene

: 93782-80-0
{[(1E,5E)-7-(tert-Butyl-dimethyl-silanyloxy)-1-isopropenyl-9-methyl-deca-1,5,7,8-tetraenyloxy]-dimethyl-silanyl}-benzene

Guidance literature:: With n-butyllithium; In diethyl ether; hexane; at -78 ℃; for 1h;
DOI:10.1021/ja00284a051

Reference yield:

: 3839-31-4
dimethyl(phenyl)silyllithium

: 93782-80-0
{[(1E,5E)-7-(tert-Butyl-dimethyl-silanyloxy)-1-isopropenyl-9-methyl-deca-1,5,7,8-tetraenyloxy]-dimethyl-silanyl}-benzene

Guidance literature:: Multi-step reaction with 4 steps

1: 71 percent / tetrahydrofuran; diethyl ether / 2.5 h / -78 °C

2: 83 percent / oxalyl chloride / CH₂Cl₂; dimethylsulfoxide / 1 h / Ambient temperature

3: 79 percent / LDA / tetrahydrofuran; hexane / 1 h / -78 °C

4: n-BuLi / diethyl ether; hexane / 1 h / -78 °C

With n-butyllithium; oxalyl dichloride; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; dimethyl sulfoxide;
DOI:10.1021/ja00284a051

Reference yield:

: 93782-78-6
2-methyl-1-(phenyldimethylsilyl)2-propen-1-one

: 93782-80-0
{[(1E,5E)-7-(tert-Butyl-dimethyl-silanyloxy)-1-isopropenyl-9-methyl-deca-1,5,7,8-tetraenyloxy]-dimethyl-silanyl}-benzene

Guidance literature:: Multi-step reaction with 2 steps

1: 79 percent / LDA / tetrahydrofuran; hexane / 1 h / -78 °C

2: n-BuLi / diethyl ether; hexane / 1 h / -78 °C

With n-butyllithium; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether; hexane;
DOI:10.1021/ja00284a051