N-phenyl-3-methylsalicylaldimine

Base Information

Chemical Name:N-phenyl-3-methylsalicylaldimine
CAS No.:86010-97-1
Molecular Formula:C₁₄H₁₃NO
Molecular Weight:211.263
Hs Code.:

Synonyms:N-phenyl-3-methylsalicylaldimine

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Chemical Property of N-phenyl-3-methylsalicylaldimine

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Technology Process of N-phenyl-3-methylsalicylaldimine

There total 2 articles about N-phenyl-3-methylsalicylaldimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 824-42-0
2-methoxy-3-methylbenzaldehyde

: 62-53-3
aniline

: 86010-97-1
N-phenyl-3-methylsalicylaldimine

Guidance literature:: In ethanol; for 2h; Reflux;
DOI:10.1021/ic2011452

Reference yield:

: 95-48-7,77504-84-8
ortho-cresol

: 86010-97-1
N-phenyl-3-methylsalicylaldimine

Guidance literature:: Multi-step reaction with 2 steps

1.1: EtMgBr / diethyl ether; tetrahydrofuran / 2 h / 20 °C

1.2: Et₃N / toluene / 2 h / 95 °C

2.1: 3 Angstroem sieves / ethanol / 16 h / 20 °C

With 3 A molecular sieve; ethylmagnesium bromide; In tetrahydrofuran; diethyl ether; ethanol;
DOI:10.1021/ja0032780

Reference yield: 75.0%

: 7550-45-0
titanium tetrachloride

: 86010-97-1
N-phenyl-3-methylsalicylaldimine

: bis[N-(3-methylsalicylidene)anilinato]titanium(IV)dichloride

Guidance literature:: With n-butyllithium; In diethyl ether; hexane; n-heptane; (Ar); to a stirred soln. of ligand in dry diethyl ether at -78°C added n-BuLi in hexane dropwise for 5 min, warmed to room temp. stirred for 6 h, added dropwise to TiCl4 in heptane for 20 min in diethyl ether at -78°C, warmed to room temp; concd., added CH2Cl2, stirred for 15 min, filtered, washed (n-hexane), organic filtrates concd.(vac.), washed (n-hexane), filtered, dried (vac.), elem. anal.;
DOI:10.1016/S1381-1169(03)00096-7