allyl-cyclohex-1-enyl-malononitrile

Base Information

• Chemical Name: allyl-cyclohex-1-enyl-malononitrile
• CAS No.: 19719-69-8
• Molecular Formula: C₁₂H₁₄N₂
• Molecular Weight: 186.257
• Mol file: 19719-69-8.mol

Synonyms:allyl-cyclohex-1-enyl-malononitrile

Chemical Property of allyl-cyclohex-1-enyl-malononitrile

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of allyl-cyclohex-1-enyl-malononitrile

There total 6 articles about allyl-cyclohex-1-enyl-malononitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

2-dicyanomethylene-cyclohexanecarboxylic acid allyl ester → allyl-cyclohex-1-enyl-malononitrile (19719-69-8)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In dichloromethane; at 20 ℃; for 1.5h;

DOI:10.1002/anie.200600721

Reference yield:

2-(cyclohex-1-en-1-yl)-2-(prop-2-yn-1-yl)malononitrile (64686-38-0) → allyl-cyclohex-1-enyl-malononitrile (19719-69-8)

Guidance literature:

With quinoline; hydrogen; palladium on barium sulfate;

DOI:10.1016/S0040-4020(01)92603-1

Reference yield:

2-allylcyclohexan-1-one (94-66-6) → allyl-cyclohex-1-enyl-malononitrile (19719-69-8)

Guidance literature:

Multi-step reaction with 2 steps

1: AcOH, β-alanine

2: ethanol / Irradiation

With acetic acid; 3-amino propanoic acid; In ethanol;

DOI:10.1016/S0040-4020(01)92603-1

upstream raw materials:

2-(cyclohexylidene)malononitrile

sodium ethanolate

allyl bromide

2-(cyclohex-1-en-1-yl)-2-(prop-2-yn-1-yl)malononitrile

Downstream raw materials:

(2-allyl-cyclohexylidene)-malononitrile

Refernces