methyl 3-{2-[2,2-bis(methoxycarbonyl)hexa-4,5-dienyl]phenyl}-2-(methoxycarbonyl)propionate

Base Information

Chemical Name:methyl 3-{2-[2,2-bis(methoxycarbonyl)hexa-4,5-dienyl]phenyl}-2-(methoxycarbonyl)propionate
CAS No.:1187427-49-1
Molecular Formula:C₂₂H₂₆O₈
Molecular Weight:418.444
Hs Code.:

Synonyms:methyl 3-{2-[2,2-bis(methoxycarbonyl)hexa-4,5-dienyl]phenyl}-2-(methoxycarbonyl)propionate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 3-{2-[2,2-bis(methoxycarbonyl)hexa-4,5-dienyl]phenyl}-2-(methoxycarbonyl)propionate

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Technology Process of methyl 3-{2-[2,2-bis(methoxycarbonyl)hexa-4,5-dienyl]phenyl}-2-(methoxycarbonyl)propionate

There total 1 articles about methyl 3-{2-[2,2-bis(methoxycarbonyl)hexa-4,5-dienyl]phenyl}-2-(methoxycarbonyl)propionate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 1204707-17-4
dimethyl 2-(2-bromomethylbenzyl)-2-buta-2,3-dienylmalonate

: 108-59-8
malonic acid dimethyl ester

: 1187427-49-1
methyl 3-{2-[2,2-bis(methoxycarbonyl)hexa-4,5-dienyl]phenyl}-2-(methoxycarbonyl)propionate

Guidance literature:: With sodium hydride; In tetrahydrofuran; mineral oil; at 80 ℃; for 10.8h; Inert atmosphere;
DOI:10.1002/chem.200900972

Reference yield: 91.0%

: 591-50-4
iodobenzene

: 1187427-49-1
methyl 3-{2-[2,2-bis(methoxycarbonyl)hexa-4,5-dienyl]phenyl}-2-(methoxycarbonyl)propionate

: 1187427-50-4
tetramethyl 8-phenyl-5,7,10,12-tetrahydrobenzocyclodec-8(E)-ene-6,6,11,11-tetracarboxylate

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In N,N-dimethyl acetamide; at 80 ℃; stereoselective reaction; Inert atmosphere; Cooling with acetone-dry ice;
DOI:10.1002/chem.200900972

Reference yield: 90.0%

: 624-31-7
4-tolyl iodide

: 1187427-49-1
methyl 3-{2-[2,2-bis(methoxycarbonyl)hexa-4,5-dienyl]phenyl}-2-(methoxycarbonyl)propionate

: 1187427-54-8
tetramethyl (8-p-tolyl)-5,7,10,12-tetrahydrobenzocyclodec-8(E)-ene-6,6,11,11-tetracarboxylate

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In N,N-dimethyl acetamide; at 80 ℃; stereoselective reaction; Inert atmosphere; Cooling with acetone-dry ice;
DOI:10.1002/chem.200900972