2-methoxyphenyl-4-amino-2-nitro-5-methylphenyl sulfide

Base Information

Chemical Name:2-methoxyphenyl-4-amino-2-nitro-5-methylphenyl sulfide
CAS No.:381229-50-1
Molecular Formula:C₁₄H₁₄N₂O₃S
Molecular Weight:290.343
Hs Code.:

Synonyms:2-methoxyphenyl-4-amino-2-nitro-5-methylphenyl sulfide

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Chemical Property of 2-methoxyphenyl-4-amino-2-nitro-5-methylphenyl sulfide

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Technology Process of 2-methoxyphenyl-4-amino-2-nitro-5-methylphenyl sulfide

There total 1 articles about 2-methoxyphenyl-4-amino-2-nitro-5-methylphenyl sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 7217-59-6
2-Methoxybenzenethiol

: 34648-99-2
4-chloro-2-methyl-5-nitroaniline

: 381229-50-1
2-methoxyphenyl-4-amino-2-nitro-5-methylphenyl sulfide

Guidance literature:: With caesium carbonate; In N,N-dimethyl-formamide; at 60 ℃; for 16h;
DOI:10.1021/jm0103108

Reference yield: 90.0%

: 381229-50-1
2-methoxyphenyl-4-amino-2-nitro-5-methylphenyl sulfide

: 381229-51-2
2-methoxyphenyl 4-iodo-2-nitro-5-methylphenyl sulfide

Guidance literature:: 2-methoxyphenyl-4-amino-2-nitro-5-methylphenyl sulfide; With tert.-butylnitrite; sulfuric acid; In acetonitrile; at 0 ℃; for 1h;

With urea; potassium iodide; In acetonitrile; Further stages.;
DOI:10.1021/jm0103108

Reference yield:

: 381229-50-1
2-methoxyphenyl-4-amino-2-nitro-5-methylphenyl sulfide

: 4-(2-methoxyphenylthio)-2-methyl-5-nitrocinnamic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: tert-butyl nitrite; 3N aq. H₂SO₄ / acetonitrile / 1 h / 0 °C

1.2: 90 percent / aq. KI; urea / acetonitrile

2.1: 81 percent / Pd(OAc)2; Et₃N / tetrahydrofuran / 48 h / 65 °C

With palladium diacetate; tert.-butylnitrite; sulfuric acid; triethylamine; In tetrahydrofuran; acetonitrile; 2.1: Heck reaction;
DOI:10.1021/jm0103108