1,1,2-Triphenyl-2-(4- bromomethylphenyl)ethylene

Base Information

• Chemical Name: 1,1,2-Triphenyl-2-(4- bromomethylphenyl)ethylene
• CAS No.: 1361969-01-8
• Molecular Formula: C₂₇H₂₁Br
• Molecular Weight: 425.368
• Mol file: 1361969-01-8.mol

Synonyms:(2-(4-(bromomethyl)phenyl)ethene-1,1,2-triyl)tribenzene

Chemical Property of 1,1,2-Triphenyl-2-(4- bromomethylphenyl)ethylene

Chemical Property:

• Boiling Point: 478.7±14.0 °C(Predicted)
• Density: 1.269±0.06 g/cm3(Predicted)
• Storage Temp.: 2-8°C

Purity/Quality:

99.0% ^*data from raw suppliers

(2-(4-(Bromomethyl)phenyl)ethene-1,1,2-triyl)tribenzene 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,1,2-Triphenyl-2-(4- bromomethylphenyl)ethylene

There total 10 articles about 1,1,2-Triphenyl-2-(4- bromomethylphenyl)ethylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

4-(1,2,2-triphenylethenyl)benzenemethanol (1015082-83-3) → (2-(4-(bromomethyl)phenyl)ethene-1,1,2-triyl)tribenzene (1361969-01-8)

Guidance literature:

With phosphorus tribromide; In chloroform; at 0 ℃; for 1h;

DOI:10.1002/chem.202104024

Reference yield: 74.0%

1,1,2-triphenyl-2-(p-methylphenyl)ethylene (70592-06-2) → (2-(4-(bromomethyl)phenyl)ethene-1,1,2-triyl)tribenzene (1361969-01-8)

Guidance literature:

With N-Bromosuccinimide; dibenzoyl peroxide; In chloroform; for 14h; Reflux;

Reference yield: 56.0%

N-Bromosuccinimide (128-08-5) + 1,1,2-triphenyl-2-(p-methylphenyl)ethylene (70592-06-2) → (2-(4-(bromomethyl)phenyl)ethene-1,1,2-triyl)tribenzene (1361969-01-8)

Guidance literature:

With dibenzoyl peroxide; In tetrachloromethane; at 80 ℃; for 24h;

DOI:10.1039/c8dt04898c

upstream raw materials:

Diphenylmethane

4-Methylbenzophenone

1,1,2-triphenyl-2-(p-methylphenyl)ethylene

1-(4-methylphenyl)-1,2,2-triphenylethanol

Downstream raw materials:

1-[4-(triethylammoniomethyl)phenyl]-1,2,2-triphenylethene bromide

(2-(4-(azidomethyl)phenyl)ethene-1,1,2-triyl)tribenzene

2-[4-(1,2,2-triphenylvinyl)phenyl]acetonitrile

Refernces

• 1、 Tian, Yuan,Wang, Zhao-Yang,Zang, Shuang-Quan,Li, Dan,Mak, Thomas C. W.. "Luminescent cyclic trinuclear coinage metal complexes with aggregation-induced emission (AIE) performance". . p. 2275 - 2279. Retrieved 2019.
• 2、 Liu, Shunjie,Cheng, Yanhua,Zhang, Haoke,Qiu, Zijie,Kwok, Ryan T. K.,Lam, Jacky W. Y.,Tang, Ben Zhong. "In Situ Monitoring of RAFT Polymerization by Tetraphenylethylene-Containing Agents with Aggregation-Induced Emission Characteristics". . p. 6274 - 6278. Retrieved 2018.
• 3、 Wu, Jianbin,Huang, Songyang,Gao, Yan,Li, Jiale,Wang, Xi. "Inducing the distinctly different fluorescence properties of a tetraphenylethene (TPE) derivative modified lanthanide nanowire upon the addition of a pair of: Cis- A nd trans-isomers of fatty acids". . p. 16902 - 16908. Retrieved 2018.
• 4、 Krishnan, Nithiyanandan,Ameena, M A Hanna,Atchimnaidu, Siriki,Perumal, Devanathan,Golla, Murali,Krishna, Jithu,Varghese, Reji. "Self-assembly of tetraphenylethylene-based dendron into blue fluorescent nanoparticles with aggregation induced enhanced emission §". . . Retrieved 2018.
• 5、 Gao, Yan,Han, Bin,Chen, Yuting,Wang, Xi,Bai, Ming. "Phenylcarboxyl-decorated tetraphenylethene with diverse molecular RIM-induced emission from host-guest inclusion and aggregation formation". . p. 16581 - 16585. Retrieved 2016.
• 6、 Du, Xu-Sheng,Han, Ying,Chen, Chuan-Feng. "Helic[6]arene-Based Chiral Pseudo[1]rotaxanes and [1]Rotaxanes". . . Retrieved 2021/12/14.