ethyl 1-(2-(4-bromobenzoyl)hydrazinecarboxamido)-2,2-dimethylcyclopropanecarboxylate

Base Information

Chemical Name:ethyl 1-(2-(4-bromobenzoyl)hydrazinecarboxamido)-2,2-dimethylcyclopropanecarboxylate
CAS No.:1254254-05-1
Molecular Formula:C₁₆H₂₀BrN₃O₄
Molecular Weight:398.256
Hs Code.:

Synonyms:ethyl 1-(2-(4-bromobenzoyl)hydrazinecarboxamido)-2,2-dimethylcyclopropanecarboxylate

Suppliers and Price of ethyl 1-(2-(4-bromobenzoyl)hydrazinecarboxamido)-2,2-dimethylcyclopropanecarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of ethyl 1-(2-(4-bromobenzoyl)hydrazinecarboxamido)-2,2-dimethylcyclopropanecarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of ethyl 1-(2-(4-bromobenzoyl)hydrazinecarboxamido)-2,2-dimethylcyclopropanecarboxylate

There total 5 articles about ethyl 1-(2-(4-bromobenzoyl)hydrazinecarboxamido)-2,2-dimethylcyclopropanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 1060639-85-1
ethyl 1-isocyanato-2,2-dimethylcyclopropanecarboxylate

: 5933-32-4
4-bromobenzoic acid hydrazide

: 1254254-05-1
ethyl 1-(2-(4-bromobenzoyl)hydrazinecarboxamido)-2,2-dimethylcyclopropanecarboxylate

Guidance literature:: at 20 ℃;
DOI:10.1016/j.ejmech.2012.05.037

Reference yield:

: C₁₂H₁₈O₆

: 1254254-05-1
ethyl 1-(2-(4-bromobenzoyl)hydrazinecarboxamido)-2,2-dimethylcyclopropanecarboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: sodium azide / tetrahydrofuran; water / 1 h / -15 - -10 °C

2: toluene / 75 °C

3: 20 °C

With sodium azide; In tetrahydrofuran; water; toluene; 2: Curtius rearrangement;
DOI:10.1016/j.ejmech.2012.05.037

Reference yield:

: 16783-05-4
diethyl 2,2-dimethyl cyclopropane 1,1-dicarboxylate

: 1254254-05-1
ethyl 1-(2-(4-bromobenzoyl)hydrazinecarboxamido)-2,2-dimethylcyclopropanecarboxylate

Guidance literature:: Multi-step reaction with 5 steps

1.1: sodium hydroxide / ethanol / 12 h / 20 °C

1.2: Saturated solution

2.1: 4-methyl-morpholine / tetrahydrofuran / 0.33 h / -15 °C

3.1: sodium azide / tetrahydrofuran; water / 1 h / -15 - -10 °C

4.1: toluene / 75 °C

5.1: 20 °C

With 4-methyl-morpholine; sodium azide; sodium hydroxide; In tetrahydrofuran; ethanol; water; toluene; 4.1: Curtius rearrangement;
DOI:10.1016/j.ejmech.2012.05.037