benzyl N-(2,2,4-triphenylpent-4-en-1-yl)sulfamoylcarbamate

Base Information

• Chemical Name: benzyl N-(2,2,4-triphenylpent-4-en-1-yl)sulfamoylcarbamate
• CAS No.: 958264-21-6
• Molecular Formula: C₃₁H₃₀N₂O₄S
• Molecular Weight: 526.656
• Mol file: 958264-21-6.mol

Synonyms:benzyl N-(2,2,4-triphenylpent-4-en-1-yl)sulfamoylcarbamate

Chemical Property of benzyl N-(2,2,4-triphenylpent-4-en-1-yl)sulfamoylcarbamate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of benzyl N-(2,2,4-triphenylpent-4-en-1-yl)sulfamoylcarbamate

There total 1 articles about benzyl N-(2,2,4-triphenylpent-4-en-1-yl)sulfamoylcarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

N-benzyloxycarbonyl-N'-(4-[dimethylazaniumylidene]-1,4-dihydropyridin-1-ylsulfonyl)azanide (1037211-09-8) + 2,2,4-triphenylpent-4-en-1-amine (1000848-80-5) → benzyl N-(2,2,4-triphenylpent-4-en-1-yl)sulfamoylcarbamate (958264-21-6)

Guidance literature:

In dichloromethane; Inert atmosphere; Schlenk technique;

DOI:10.1002/chem.201403891

Reference yield: 75.0%

benzyl N-(2,2,4-triphenylpent-4-en-1-yl)sulfamoylcarbamate (958264-21-6) → (S)-benzyl 3a,5,5-triphenyltetrahydropyrrolo[1,2-b][1,2,5]thiadiazole-2(3H)-carboxylate-1,1-dioxide (1648743-87-6)

Guidance literature:

benzyl N-(2,2,4-triphenylpent-4-en-1-yl)sulfamoylcarbamate; With (R)-2-((2-diacetoxyiodophenyl)(methoxy)methyl)pyridine; In acetonitrile; at -48 ℃; for 0.0833333h; Inert atmosphere; Schlenk technique;

With trimethylsilyl trifluoromethanesulfonate; boron trifluoride diethyl etherate; In acetonitrile; at -48 ℃; for 5h; enantioselective reaction; Inert atmosphere; Schlenk technique;

DOI:10.1002/chem.201403891

Reference yield: 72.0%

benzyl N-(2,2,4-triphenylpent-4-en-1-yl)sulfamoylcarbamate (958264-21-6) → C31H28N2O4S (958264-36-3)

Guidance literature:

With [bis(acetoxy)iodo]benzene; sodium acetate; nickel dichloride; In N,N-dimethyl-formamide; at 40 ℃;

DOI:10.1002/anie.200702160

upstream raw materials:

N-benzyloxycarbonyl-N'-(4-[dimethylazaniumylidene]-1,4-dihydropyridin-1-ylsulfonyl)azanide

2,2,4-triphenylpent-4-en-1-amine

Downstream raw materials:

C₃₁H₂₈N₂O₄S

(S)-benzyl 3a,5,5-triphenyltetrahydropyrrolo[1,2-b][1,2,5]thiadiazole-2(3H)-carboxylate-1,1-dioxide

(R)-benzyl 3a,5,5-triphenyltetrahydropyrrolo[1,2-b][1,2,5]thiadiazole-2(3H)-carboxylate-1,1-dioxide

(S)-(2,4,4-triphenylpyrrolidin-2-yl)methanamine