(2α,3S,4R,5R,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-2-vinyltetrahydro-2H-pyran-3-ol

Base Information

• Chemical Name: (2α,3S,4R,5R,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-2-vinyltetrahydro-2H-pyran-3-ol
• CAS No.: 294872-82-5
• Molecular Formula: C₂₉H₃₂O₅
• Molecular Weight: 460.57

Synonyms:(2α,3S,4R,5R,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-2-vinyltetrahydro-2H-pyran-3-ol

Chemical Property of (2α,3S,4R,5R,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-2-vinyltetrahydro-2H-pyran-3-ol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2α,3S,4R,5R,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-2-vinyltetrahydro-2H-pyran-3-ol

There total 7 articles about (2α,3S,4R,5R,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-2-vinyltetrahydro-2H-pyran-3-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

trivinyl aluminum (1115-97-5) + 3,4,6-tri-O-benzyl-D-glucal epoxide (74372-90-0) → (2α,3S,4R,5R,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-2-vinyltetrahydro-2H-pyran-3-ol (294872-82-5)

Guidance literature:

at -65 - 20 ℃;

DOI:10.1016/S0040-4020(02)00057-1

Reference yield: 50.0%

vinyl magnesium bromide (1826-67-1) + 3,4,6-tri-O-benzyl-D-glucal epoxide (74372-90-0) → (2α,3S,4R,5R,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-2-vinyltetrahydro-2H-pyran-3-ol (294872-82-5)

Guidance literature:

vinyl magnesium bromide; With zinc(II) chloride; In tetrahydrofuran; for 24h;

3,4,6-tri-O-benzyl-D-glucal epoxide; In tetrahydrofuran;

DOI:10.1081/CAR-120026458

Reference yield: 40.0%

3,4,6-tri-O-benzyl-D-glucal epoxide (74372-90-0) + dimethylvinyl aluminum → (2α,3S,4R,5R,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-2-vinyltetrahydro-2H-pyran-3-ol (294872-82-5) + (3S,4R,5S,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-methyl-tetrahydro-pyran-3-ol (1005763-00-7)

Guidance literature:

at -65 - 20 ℃;

DOI:10.1016/S0040-4020(02)00057-1

upstream raw materials:

trivinyl aluminum

3,4,6-tri-O-benzyl-D-glucal epoxide

vinyl magnesium bromide

3,4,6-tri-O-benzyl-D-glucal

Downstream raw materials:

((2R,3S,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-2-vinyl-tetrahydro-pyran-3-yloxy)-((2R,3R,4R,5R,6S)-4,5-bis-benzyloxy-6-methoxy-2-vinyl-tetrahydro-pyran-3-yloxy)-dimethyl-silane

1-deoxy-1-α-hydroxymethyl-2-O-(tert-butyldimethylsilyl)-3,4,5-tri-O-benzyl-D-glucose

Methanesulfonic acid (2R,3S,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-ylmethyl ester

C₃₄H₄₂NO₉P

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 294872-82-5 (2α,3S,4R,5R,6R)-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)-2-vinyltetrahydro-2H-pyran-3-ol

Send

Send

Metric Ton KG G Pound L ML

Send

Send