Technology Process of 3-(2-deuterophenyl)propyl tert-butyl peroxide
There total 4 articles about 3-(2-deuterophenyl)propyl tert-butyl peroxide which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
3-(2-iodophenyl)propyl tert-butyl peroxide;
With
n-butyllithium;
In
tetrahydrofuran; hexane;
at -78 ℃;
for 0.0833333h;
Inert atmosphere;
With
d(4)-methanol;
In
tetrahydrofuran; hexane;
Inert atmosphere;
DOI:10.1021/ja5026276
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: sodium tetrahydroborate; boron trifluoride diethyl etherate / tetrahydrofuran / 1 h / 0 °C / Inert atmosphere
1.2: Inert atmosphere
2.1: triethylamine / dichloromethane / 0 - 20 °C / Inert atmosphere
3.1: cesiumhydroxide monohydrate / N,N-dimethyl-formamide / 0 °C / Inert atmosphere
3.2: 0 - 20 °C / Inert atmosphere
4.1: n-butyllithium / tetrahydrofuran; hexane / 0.08 h / -78 °C / Inert atmosphere
4.2: Inert atmosphere
With
sodium tetrahydroborate; n-butyllithium; cesiumhydroxide monohydrate; boron trifluoride diethyl etherate; triethylamine;
In
tetrahydrofuran; hexane; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja5026276
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: triethylamine / dichloromethane / 0 - 20 °C / Inert atmosphere
2.1: cesiumhydroxide monohydrate / N,N-dimethyl-formamide / 0 °C / Inert atmosphere
2.2: 0 - 20 °C / Inert atmosphere
3.1: n-butyllithium / tetrahydrofuran; hexane / 0.08 h / -78 °C / Inert atmosphere
3.2: Inert atmosphere
With
n-butyllithium; cesiumhydroxide monohydrate; triethylamine;
In
tetrahydrofuran; hexane; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja5026276
