(S)-(+)-2-[(dimethyl)(vinyl)silyloxy]-3-methylbutanal N,N-diphenylhydrazone

Base Information

Chemical Name:(S)-(+)-2-[(dimethyl)(vinyl)silyloxy]-3-methylbutanal N,N-diphenylhydrazone
CAS No.:324753-60-8
Molecular Formula:C₂₁H₂₈N₂OSi
Molecular Weight:352.552
Hs Code.:

Synonyms:(S)-(+)-2-[(dimethyl)(vinyl)silyloxy]-3-methylbutanal N,N-diphenylhydrazone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S)-(+)-2-[(dimethyl)(vinyl)silyloxy]-3-methylbutanal N,N-diphenylhydrazone

Chemical Property:

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Technology Process of (S)-(+)-2-[(dimethyl)(vinyl)silyloxy]-3-methylbutanal N,N-diphenylhydrazone

There total 4 articles about (S)-(+)-2-[(dimethyl)(vinyl)silyloxy]-3-methylbutanal N,N-diphenylhydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 1719-58-0
Chlorodimethylvinylsilane

: 324753-55-1
(S)-(+)-2-hydroxy-3-methylbutanal N,N-diphenylhydrazone

: 324753-60-8
(S)-(+)-2-[(dimethyl)(vinyl)silyloxy]-3-methylbutanal N,N-diphenylhydrazone

Guidance literature:: With triethylamine; In dichloromethane; at 0 - 20 ℃; for 5h;
DOI:10.1021/jo035405r

Reference yield:

: 136779-39-0
(S)-methyl 2-(tert-butyldimethylsilyloxy)-3-methylbutanal

: 324753-60-8
(S)-(+)-2-[(dimethyl)(vinyl)silyloxy]-3-methylbutanal N,N-diphenylhydrazone

Guidance literature:: Multi-step reaction with 3 steps

1: 0.756 g / pyridine / toluene / 20 °C

2: 88 percent / Bu₄NF / tetrahydrofuran / 20 °C

3: 92 percent / Et₃N / CH₂Cl₂ / 5 h / 0 - 20 °C

With pyridine; tetrabutyl ammonium fluoride; triethylamine; In tetrahydrofuran; dichloromethane; toluene;
DOI:10.1021/jo035405r

Reference yield:

: 228716-82-3
(S)-2-(tert-butyldimethylsilanyloxy)-3-methylbutyric acid methyl ester

: 324753-60-8
(S)-(+)-2-[(dimethyl)(vinyl)silyloxy]-3-methylbutanal N,N-diphenylhydrazone

Guidance literature:: Multi-step reaction with 4 steps

1: diisobutylaluminum hydride / hexane; toluene / 1.5 h / -78 °C

2: 0.756 g / pyridine / toluene / 20 °C

3: 88 percent / Bu₄NF / tetrahydrofuran / 20 °C

4: 92 percent / Et₃N / CH₂Cl₂ / 5 h / 0 - 20 °C

With pyridine; tetrabutyl ammonium fluoride; diisobutylaluminium hydride; triethylamine; In tetrahydrofuran; hexane; dichloromethane; toluene;
DOI:10.1021/jo035405r