(1-Iodomethylene)cyclopentane

Base Information

• Chemical Name: (1-Iodomethylene)cyclopentane
• CAS No.: 23904-34-9
• Molecular Formula: C₆H₉I
• Molecular Weight: 208.042
• Mol file: 23904-34-9.mol

Synonyms:(1-Iodomethylene)cyclopentane

Chemical Property of (1-Iodomethylene)cyclopentane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (1-Iodomethylene)cyclopentane

There total 1 articles about (1-Iodomethylene)cyclopentane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(Diiodomethyl)cyclopentane (85390-84-7) → 1-methylcyclopent-1-ene (693-89-0) + (1-Iodomethylene)cyclopentane (23904-34-9) + (dimethoxymethyl)cyclopentane (20117-79-7) + cyclohexene (110-83-8)

Guidance literature:

In diethyl ether; for 12h; Product distribution; Irradiation; variation of solvent and time;

DOI:10.1021/jo00160a029

Reference yield: 98.0%

(1-Iodomethylene)cyclopentane (23904-34-9) + phenylacetylene (536-74-3) → (3-cyclopentylideneprop-1-ynyl)benzene

Guidance literature:

With iodo(4,5-bis(diphenylphosphano)-9,9-dimethylxanthene)copper(I); caesium carbonate; In 1,4-dioxane; at 135 ℃; Inert atmosphere;

DOI:10.1055/s-0031-1290502

Reference yield: 45.0%

(1-Iodomethylene)cyclopentane (23904-34-9) + p-Chlorothiophenol (106-54-7) → C12H13ClS (1384172-77-3) + (4-chlorophenyl)(cyclopentenylmethyl)sulfane (1384172-78-4)

Guidance literature:

With iron(III) chloride; potassium tert-butylate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; In 1,4-dioxane; N,N-dimethyl-formamide; at 135 ℃; for 24h; Inert atmosphere;

DOI:10.1021/jo3008397

upstream raw materials:

(Diiodomethyl)cyclopentane

Downstream raw materials:

1,3-dioxolane-2-spirocyclohexane

methylenecyclopentane

1-chlorocyclohexene

C₁₂H₁₃ClS

Refernces