bis[N-2,6-diisopropylphenyl-N-trimethylsilylamido]bis(tetrahydrofuran)samarium(II)

Base Information

Chemical Name:bis[N-2,6-diisopropylphenyl-N-trimethylsilylamido]bis(tetrahydrofuran)samarium(II)
CAS No.:188599-73-7
Molecular Formula:C₃₈H₆₈N₂O₂Si₂Sm
Molecular Weight:791.501
Hs Code.:

Synonyms:bis[N-2,6-diisopropylphenyl-N-trimethylsilylamido]bis(tetrahydrofuran)samarium(II)

Suppliers and Price of bis[N-2,6-diisopropylphenyl-N-trimethylsilylamido]bis(tetrahydrofuran)samarium(II)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of bis[N-2,6-diisopropylphenyl-N-trimethylsilylamido]bis(tetrahydrofuran)samarium(II)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of bis[N-2,6-diisopropylphenyl-N-trimethylsilylamido]bis(tetrahydrofuran)samarium(II)

There total 3 articles about bis[N-2,6-diisopropylphenyl-N-trimethylsilylamido]bis(tetrahydrofuran)samarium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 945487-29-6
SmCl₃(N(C₆H₃(CH(CH₃)2)2)Si(CH₃)3)2Li₂(OC₄H₈)4

: 188599-73-7
bis[N-2,6-diisopropylphenyl-N-trimethylsilylamido]bis(tetrahydrofuran)samarium(II)

Guidance literature:: With Na-K alloy; In tetrahydrofuran; toluene; byproducts: NaCl, LiCl; under Ar; Na-K alloy in toluene added to soln. of Sm complex in THF; stirred at 40°C for 48 h; centrifuged; solvent removed; extd. with toluene; centrifuged; crystd. at room temp.; elem. anal.;
DOI:10.1021/ic070162x

Reference yield: 3.0%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 7440-19-9
samarium

: 78923-65-6
N-trimethylsilyl-2,6-diisopropylaniline

: 188599-73-7
bis[N-2,6-diisopropylphenyl-N-trimethylsilylamido]bis(tetrahydrofuran)samarium(II)

Guidance literature:: With Hg(C₆H₅)2; Hg; In tetrahydrofuran; (inert atmosphere); stirring (65°C, 20 h); filtration (Celite), solvent removal (vac.), washing (light petroleum), recrystn. (hot light petroleum);
DOI:10.1002/cber.19971300316

Reference yield:

: 134208-71-2
lithium (2,6-diisopropylphenyl)(trimethylsilyl)amide

: 188599-73-7
bis[N-2,6-diisopropylphenyl-N-trimethylsilylamido]bis(tetrahydrofuran)samarium(II)

Guidance literature:: Multi-step reaction with 2 steps

1: diethyl ether

2: tetrahydrofuran

In tetrahydrofuran; diethyl ether;
DOI:10.1002/cber.19971300316