[1,3-bis(diphenylphosphino)propane](hept-6-en-1-ide)2Pt(II)

Base Information

• Chemical Name: [1,3-bis(diphenylphosphino)propane](hept-6-en-1-ide)2Pt(II)
• CAS No.: 944284-28-0
• Molecular Formula: C₄₁H₅₂P₂Pt
• Molecular Weight: 801.891
• Mol file: 944284-28-0.mol

Synonyms:[1,3-bis(diphenylphosphino)propane](hept-6-en-1-ide)2Pt(II)

Chemical Property of [1,3-bis(diphenylphosphino)propane](hept-6-en-1-ide)2Pt(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [1,3-bis(diphenylphosphino)propane](hept-6-en-1-ide)2Pt(II)

There total 1 articles about [1,3-bis(diphenylphosphino)propane](hept-6-en-1-ide)2Pt(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

dichloro( 1,5-cyclooctadiene)platinum(ll) (12080-32-9) + 1,3-bis-(diphenylphosphino)propane (6737-42-4) + hept-6-en-1-ylmagnesium bromide (154920-12-4) → [1,3-bis(diphenylphosphino)propane](hept-6-en-1-ide)2Pt(II) (944284-28-0)

Guidance literature:

In diethyl ether; soln. of 1-heptenylMgBr in Et2O added to soln. of (cod)PtCl2 (2.806:0.791 mol) in Et2O at -78°C; mixt. warmed to 0°C with stirring until soln. became clear; solid Ph2P(CH2)3PPh2 (0.793 mol) added; stirred for 36 h; quenched with satd. aq. soln. NH4Cl at -78°C; extd. (CH2Cl2, twice); organic layer sepd.; solvent evapd. (vac.); crystd. (CH2Cl2/hexane =3:5 vol./vol., -10°C for 48 h); decanted from mother liquor; dri ed. (vac.); elem. anal; XRD;

DOI:10.1002/anie.200604979

Reference yield: 81.0%

[1,3-bis(diphenylphosphino)propane](hept-6-en-1-ide)2Pt(II) (944284-28-0) → cis-[Pt(2-heptenyl)2(1,3-bis(diphenylphosphino)propane)] (959934-93-1)

Guidance literature:

In toluene; Pt complex in toluene was heated at 110°C for 24 h under reduced pressure; volatiles were removed, residue was crystd. from n-hexane at -10°C and recrystd. from CH2Cl2-n-hexane; elem. anal.;

DOI:10.1021/om0611249

upstream raw materials:

dichloro( 1,5-cyclooctadiene)platinum(ll)

1,3-bis-(diphenylphosphino)propane

hept-6-en-1-ylmagnesium bromide

Downstream raw materials:

cis-[Pt(2-heptenyl)2(1,3-bis(diphenylphosphino)propane)]