bis(1,3-dichloro-2-azulenyl)phenylbismuthane

Base Information

Chemical Name:bis(1,3-dichloro-2-azulenyl)phenylbismuthane
CAS No.:827347-29-5
Molecular Formula:C₂₆H₁₅BiCl₄
Molecular Weight:678.197
Hs Code.:

Synonyms:bis(1,3-dichloro-2-azulenyl)phenylbismuthane

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Chemical Property of bis(1,3-dichloro-2-azulenyl)phenylbismuthane

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Technology Process of bis(1,3-dichloro-2-azulenyl)phenylbismuthane

There total 4 articles about bis(1,3-dichloro-2-azulenyl)phenylbismuthane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 827347-28-4
chlorobis(1,3-dichloro-2-azulenyl)bismuthane

: 100-58-3
phenylmagnesium bromide

: 827347-29-5
bis(1,3-dichloro-2-azulenyl)phenylbismuthane

Guidance literature:: In tetrahydrofuran; under Ar atm. to soln. Bi compound in THF at 0°C soln. PhMgBr in THF was added and stirred for 3 h, during which time temp. was rised to ambient; react. was quenched with brine, extd. with EtOAc, dried over Na2SO4, evapd., and recrystd. from MeOH;
DOI:10.1021/om040053f

Reference yield: 73.0%

: 14658-94-7
1,3-dichloroazulene

: 7205-00-7
phenylbismuth dichloride

: 827347-29-5
bis(1,3-dichloro-2-azulenyl)phenylbismuthane

Guidance literature:: With lithium 2,2,6,6-tetramethylpiperidide; In tetrahydrofuran; under Ar atm. to soln. lithium 2,2,6,6-tetramethylpiperidide in THF at -70°C soln. 1,3-dichloroazulene was added, soln. PhBiCl2 in THF was added and stirred for 5 min; elem. anal.;
DOI:10.1021/om040053f

Reference yield:

: 14658-94-7
1,3-dichloroazulene

: 827347-29-5
bis(1,3-dichloro-2-azulenyl)phenylbismuthane

Guidance literature:: Multi-step reaction with 2 steps

1: lithium 2,2,6,6-tetramethylpiperidide / tetrahydrofuran

2: tetrahydrofuran

With lithium 2,2,6,6-tetramethylpiperidide; In tetrahydrofuran;
DOI:10.1021/om040053f