O-(Diphenylphosphinyl)hydroxylamine

Base Information Edit

Chemical Name:O-(Diphenylphosphinyl)hydroxylamine
CAS No.:72804-96-7
Molecular Formula:C12H12 N O2 P
Molecular Weight:233.207
Hs Code.:2931900090
European Community (EC) Number:810-371-8
UNII:2O9PF20T75
DSSTox Substance ID:DTXSID40449717
Nikkaji Number:J1.795.719H
Wikidata:Q27255215
Mol file:72804-96-7.mol

Synonyms:72804-96-7;O-DIPHENYLPHOSPHINYLHYDROXYLAMINE;O-(Diphenylphosphinyl)hydroxylamine;(Aminooxy)diphenylphosphine oxide;O-(diphenylphosphoryl)hydroxylamine;Hydroxylamine, O-(diphenylphosphinyl)-;amino diphenylphosphinate;O-diphenylphosphorylhydroxylamine;C12H12NO2P;(aminooxy)(diphenyl)phosphine oxide;o-(diphenylphosphinyl) hydroxylamine;O-(Diphenylphosphinyl)hydroxylamine [MI];UNII-2O9PF20T75;2O9PF20T75;MFCD12755701;O-(diphenylphosphinyl)-Hydroxylamine;SCHEMBL276503;DTXSID40449717;O-diphenylphosphinyl hydroxylamine;SJECIYLGISUNRO-UHFFFAOYSA-N;Diphenylphosphinic acid amino ester;O-diphenyl-phosphoryl-hydroxylamine;AMY20609;BCP17436;o-(diphenylphosphoryl) hydroxylamine;O-(diphenyl-phosphinyl)hydroxylamine;O-(diphenylphosphoryl)-hydroxylamine;(aminooxy)(diphenyl) phosphine oxide;AKOS015855116;GS-3968;SY018268;CS-0033557;FT-0660505;A19105;EN300-101508;O-(Diphenylphosphinyl)hydroxylamine, >=90% (HPLC);Q27255215

Suppliers and Price of O-(Diphenylphosphinyl)hydroxylamine

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
O-Diphenylphosphinylhydroxylamine
1g
$ 45.00

Sigma-Aldrich
O-(Diphenylphosphinyl)hydroxylamine ≥90% (HPLC)
1g
$ 185.00

Sigma-Aldrich
O-(Diphenylphosphinyl)hydroxylamine ≥90% (HPLC)
5g
$ 235.00

Matrix Scientific
O-Diphenylphosphinylhydroxylamine 95+%
1g
$ 68.00

Matrix Scientific
O-Diphenylphosphinylhydroxylamine 95+%
5g
$ 215.00

Matrix Scientific
O-Diphenylphosphinylhydroxylamine 95+%
25g
$ 440.00

ChemSupplyAustralia
O-(Diphenylphosphinyl)hydroxylamine, 95%
1 g
$ 71.50

ChemSupplyAustralia
O-(Diphenylphosphinyl)hydroxylamine, 95%
5 g
$ 258.50

Chemenu
O-Diphenylphosphinylhydroxylamine 95+%
100g
$ 463.00

Chemenu
O-Diphenylphosphinylhydroxylamine 95+%
25g
$ 204.00

Total 82 raw suppliers

Chemical Property of O-(Diphenylphosphinyl)hydroxylamine Edit

Chemical Property:

Melting Point:>140℃ (decomposition)
Boiling Point:368.0±25.0 °C(Predicted)
PKA:-1.65±0.70(Predicted)
PSA：62.13000
Density:1.25±0.1 g/cm3(Predicted)
LogP:2.50610
Storage Temp.:2-8°C
Solubility.:DMSO (Slightly), Methanol (Very Slightly, Sonicated)
XLogP3:1.8
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:233.06056562
Heavy Atom Count:16
Complexity:236

Purity/Quality:

98%, ^*data from raw suppliers

O-Diphenylphosphinylhydroxylamine ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)P(=O)(C2=CC=CC=C2)ON
Uses Efficient reagent for direct conversion of aldehydes to nitriles in the presence of alcohol, ketone, ester, or amine functionality. O-Diphenylphosphinylhydroxylamine is a versatile reactant used in the synthetic preparation of various products such as trans-acylaziridines and aldohydrazones.

Technology Process of O-(Diphenylphosphinyl)hydroxylamine

There total 8 articles about O-(Diphenylphosphinyl)hydroxylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: C₂₀H₁₈NO₄P

: 72804-96-7
O-(diphenylphosphinyl)hydroxylamine

Guidance literature:: With palladium on activated charcoal; hydrogen; In tetrahydrofuran; at 35 ℃; for 4h;

Reference yield: 82.0%

: 1499-21-4
Diphenylphosphinic chloride

: 72804-96-7
O-(diphenylphosphinyl)hydroxylamine

Guidance literature:: With sodium hydroxide; hydroxylamine hydrochloride; In 1,4-dioxane; water; at 0 - 22 ℃; for 0.166667h;

Reference yield: 76.0%

: 936366-71-1
tert-butyl (diphenylphosphoryl)oxycarbamate

: 72804-96-7
O-(diphenylphosphinyl)hydroxylamine

Guidance literature:: tert-butyl (diphenylphosphoryl)oxycarbamate; With methanesulfonic acid; In dichloromethane; at -5 ℃; for 2.08333h; Inert atmosphere;

With N-ethyl-N,N-diisopropylamine; In dichloromethane; at 0 - 5 ℃; Inert atmosphere;
DOI:10.15227/orgsyn.097.0054