3-benzyl-6,7-dimethoxy-1-methyl-4-phenyl-1H-naphtho[2,3-d]imidazolium-5,8-dione iodide

Base Information

• Chemical Name: 3-benzyl-6,7-dimethoxy-1-methyl-4-phenyl-1H-naphtho[2,3-d]imidazolium-5,8-dione iodide
• CAS No.: 1572419-05-6
• Molecular Formula: C₂₇H₂₃N₂O₄*I
• Molecular Weight: 566.395
• Mol file: 1572419-05-6.mol

Synonyms:3-benzyl-6,7-dimethoxy-1-methyl-4-phenyl-1H-naphtho[2,3-d]imidazolium-5,8-dione iodide

Chemical Property of 3-benzyl-6,7-dimethoxy-1-methyl-4-phenyl-1H-naphtho[2,3-d]imidazolium-5,8-dione iodide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-benzyl-6,7-dimethoxy-1-methyl-4-phenyl-1H-naphtho[2,3-d]imidazolium-5,8-dione iodide

There total 1 articles about 3-benzyl-6,7-dimethoxy-1-methyl-4-phenyl-1H-naphtho[2,3-d]imidazolium-5,8-dione iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

3-benzyl-6,7-dimethoxy-4-phenyl-1H-naphtho[2,3-d]imidazole-5,8-dione (1572419-02-3) + methyl iodide (74-88-4) → 3-benzyl-6,7-dimethoxy-1-methyl-4-phenyl-1H-naphtho[2,3-d]imidazolium-5,8-dione iodide (1572419-05-6)

Guidance literature:

In acetonitrile; at 70 ℃; for 0.25h;

DOI:10.1021/jo4027337

Reference yield: 60.0%

3-benzyl-6,7-dimethoxy-1-methyl-4-phenyl-1H-naphtho[2,3-d]imidazolium-5,8-dione iodide (1572419-05-6) → 3-benzyl-6,7-dimethoxy-1-methyl-4-phenyl-1H-naphtho[2,3-d]imidazole-2,5,8-trione (1572419-08-9)

Guidance literature:

With N-chloro-succinimide; potassium carbonate; In tetrahydrofuran; at 20 ℃; for 0.5h;

DOI:10.1021/jo4027337

Reference yield: 30.0%

tert-butylhypochlorite (507-40-4) + 3-benzyl-6,7-dimethoxy-1-methyl-4-phenyl-1H-naphtho[2,3-d]imidazolium-5,8-dione iodide (1572419-05-6) → 3-benzyl-2-tert-butylcarbonylimino-6,7-dimethoxy-1-methyl-4-phenyl-1H-naphtho[2,3-d]imidazole-2,5,8-trione (1572419-12-5)

Guidance literature:

tert-butylhypochlorite; With tert-butyl carbazate; In dichloromethane; at 20 ℃; for 0.333333h;

3-benzyl-6,7-dimethoxy-1-methyl-4-phenyl-1H-naphtho[2,3-d]imidazolium-5,8-dione iodide; With 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; at 0 - 20 ℃; for 0.5h;

DOI:10.1021/jo4027337

upstream raw materials:

3-benzyl-6,7-dimethoxy-4-phenyl-1H-naphtho[2,3-d]imidazole-5,8-dione

methyl iodide

Downstream raw materials:

3-benzyl-6,7-dimethoxy-1-methyl-4-phenyl-1H-naphtho[2,3-d]imidazole-2,5,8-trione

6,7-dimethoxy-1-methyl-4-phenyl-1H-naphtho[2,3-d]imidazole-2,5,8-trione

3-benzyl-2-tert-butylcarbonylimino-6,7-dimethoxy-1-methyl-4-phenyl-1H-naphtho[2,3-d]imidazole-2,5,8-trione