methyl 3-O-benzoyl-4,6-O-benzylidene-2-deoxy-α-D-lyxo-hexopyranoside

Base Information

• Chemical Name: methyl 3-O-benzoyl-4,6-O-benzylidene-2-deoxy-α-D-lyxo-hexopyranoside
• CAS No.: 77210-23-2
• Molecular Formula: C₂₁H₂₂O₆
• Molecular Weight: 370.402
• Mol file: 77210-23-2.mol

Synonyms:methyl 3-O-benzoyl-4,6-O-benzylidene-2-deoxy-α-D-lyxo-hexopyranoside

Chemical Property of methyl 3-O-benzoyl-4,6-O-benzylidene-2-deoxy-α-D-lyxo-hexopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 3-O-benzoyl-4,6-O-benzylidene-2-deoxy-α-D-lyxo-hexopyranoside

There total 8 articles about methyl 3-O-benzoyl-4,6-O-benzylidene-2-deoxy-α-D-lyxo-hexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

benzoyl chloride (98-88-4) + methyl 4,6-O-benzylidene-2-deoxy-α-D-lyxo-hexopyranoside (19877-02-2) → methyl 3-O-benzoyl-4,6-O-benzylidene-2-deoxy-α-D-lyxo-hexopyranoside (77210-23-2)

Guidance literature:

With pyridine; at 20 ℃; for 48h;

Reference yield: 92.0%

benzoyl chloride (98-88-4) + methyl 4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside (6752-48-3,16718-95-9,18424-62-9,19877-02-2,22886-97-1,52153-29-4,52612-68-7,55331-65-2,64978-95-6,65725-24-8,66512-93-4,67968-51-8,72904-80-4,77481-69-7,131615-73-1,138663-49-7,151214-39-0) → Methyl-3-O-benzoyl-4,6-O-benzyliden-2-desoxy-α-D-arabino-hexopyranosid (32469-89-9,64826-09-1,72348-69-7,77210-23-2,78148-01-3,75829-65-1)

Guidance literature:

In pyridine; for 12h; Ambient temperature;

DOI:10.1002/cber.19801130918

Reference yield: 49.0%

Methyl-3-O-benzoyl-4,6-benzyliden-2-O-<(methylthio)thiocarbonyl>-α-D-glucopyranosid → Methyl-3-O-benzoyl-4,6-O-benzyliden-2-desoxy-α-D-arabino-hexopyranosid (32469-89-9,64826-09-1,72348-69-7,77210-23-2,78148-01-3,75829-65-1)

Guidance literature:

With polyhydrogenmethylsiloxane; bis(tri-n-butyltin)oxide; In toluene; at 100 ℃; for 4h;

DOI:10.1002/cber.19801130918

upstream raw materials:

benzoyl chloride

methyl 4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside

methyl 3-O-benzoyl-4,6-O-benzylidene-α-D-glucopyranoside

methyl 4,6-O-benzylidene-2-deoxy-α-D-lyxo-hexopyranoside

Downstream raw materials:

methyl 3,4-di-O-benzoyl-2,6-dideoxy-α-D-lyxo-hexopyranoside

methyl 2,6-dideoxy-α-D-lyxo-hexopyranoside

methyl 3,4-di-O-benzoyl-6-bromo-2,6-dideoxy-α-D-lyxo-hexopyranoside