dicarbonylbenzyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium⁽¹⁺⁾ hexafluorophosphate

Base Information

• Chemical Name: dicarbonylbenzyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium⁽¹⁺⁾ hexafluorophosphate
• CAS No.: 99299-54-4
• Molecular Formula: C₅₀H₄₆O₂P₃Ru*F₆P
• Molecular Weight: 1017.87

Synonyms:dicarbonylbenzyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium⁽¹⁺⁾ hexafluorophosphate

Chemical Property of dicarbonylbenzyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium⁽¹⁺⁾ hexafluorophosphate

Chemical Property:

Purity/Quality:

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Technology Process of dicarbonylbenzyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium⁽¹⁺⁾ hexafluorophosphate

There total 1 articles about dicarbonylbenzyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium⁽¹⁺⁾ hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

sodium hexaflorophosphate + dicarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium(0) (37843-33-7) + benzyl bromide (100-39-0) → dicarbonylbenzyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium(1+) hexafluorophosphate (99299-54-4)

Guidance literature:

In ethanol; dichloromethane; under N2, Ru(CO)2(triphos) in CH2Cl2 treated with PhCH2Br, stirred at room temp. for 10 min, hexane added, ppt. treated with NaPF6 in EtOH; ppt. collected, washed with EtOH and Et2O, dried in vac. at 80°C; elem. anal.;

Reference yield: 73.0%

dicarbonylbenzyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium(1+) hexafluorophosphate (99299-54-4) + (+/-)sec-butyl isocyanide (14069-89-7) → RuCH2C6H5(CO)(C2H5CH(CH3)NC)(C41H39P3)(1+)*PF6(1-)=[RuCH2C6H5(CO)(C2H5CH(CH3)NC)(C41H39P3)]PF6 (102261-60-9)

Guidance literature:

With (CH₃)3NO; In dichloromethane; N2-atmosphere; addn. of (CH3)3NO to Ru complex and the isonitrile in CH2Cl2; stirring at room temp. for 25 min;; addn. of ethanol; partial evapn. under reduced pressure; addn. of Et2O;ppt. was collected, washed with ether, and dried; elem. anal.;

DOI:10.1021/om00138a014

Reference yield: 39.0%

sodium hexaflorophosphate + dicarbonylbenzyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium(1+) hexafluorophosphate (99299-54-4) + tert-butylisonitrile (119072-55-8,7188-38-7) → RuCH2C6H5(CO)((CH3)3CNC)(C41H39P3)(1+)*PF6(1-)=[RuCH2C6H5(CO)((CH3)3CNC)(C41H39P3)]PF6 (102261-58-5)

Guidance literature:

With (CH₃)3NO; In ethanol; dichloromethane; N2-atmosphere; stirring of Ru-complex, isonitrile and Me3NO in CH2Cl2 at room temp. for 0.5 h; addn. of heptane; partial evapn. under reduced pressure; dissolving of the obtained oil in EtOH contg. NaPF6; evapn. to dryness; dissolving in CH2Cl2; addn. of Et2O; cooling; ppt. was filtered off and recrystd. from acetone/EtOH; washing with Et2O; drying; elem. anal.;

DOI:10.1021/om00138a014

upstream raw materials:

dicarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium⁽⁰⁾

benzyl bromide

Downstream raw materials:

RuCH₂C₆H₅(CO)((CH₃)3CNC)(C₄₁H₃₉P₃)⁽¹⁺⁾*PF₆^(1-)=[RuCH₂C₆H₅(CO)((CH₃)3CNC)(C₄₁H₃₉P₃)]PF₆

RuCH₂C₆H₅(CO)(C₂H₅CH(CH₃)NC)(C₄₁H₃₉P₃)⁽¹⁺⁾*PF₆^(1-)=[RuCH₂C₆H₅(CO)(C₂H₅CH(CH₃)NC)(C₄₁H₃₉P₃)]PF₆

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