C₃₇H₄₆O₁₃

Base Information Edit

Chemical Name:C₃₇H₄₆O₁₃
CAS No.:1018988-52-7
Molecular Formula:C₃₇H₄₆O₁₃
Molecular Weight:698.764
Hs Code.:
Mol file:1018988-52-7.mol

C<sub>37</sub>H<sub>46</sub>O<sub>13</sub>

Synonyms:C₃₇H₄₆O₁₃

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Chemical Property of C₃₇H₄₆O₁₃ Edit

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Technology Process of C₃₇H₄₆O₁₃

There total 21 articles about C₃₇H₄₆O₁₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 100-07-2
4-methoxy-benzoyl chloride

: 3β,11α,19-triacetoxy-1β,5,14-trihydroxy-5β,14β-card-20(22)-enolide

: 1018988-52-7
C₃₇H₄₆O₁₃

Guidance literature:: With pyridine; dmap; In dichloromethane; at 40 ℃; for 18h;
DOI:10.1002/anie.200704959

Reference yield: 68.0%

: 1018988-53-8
C₃₅H₄₆O₁₃

: 73818-55-0,15596-07-3
Bestmann ylide

: 1018988-52-7
C₃₇H₄₆O₁₃

Guidance literature:: With triethylamine; In benzene; at 20 ℃; for 24h;
DOI:10.1002/anie.200704959

Reference yield:

: 1018988-59-4
C₅₂H₆₆O₇Si₂

: 1018988-52-7
C₃₇H₄₆O₁₃

Guidance literature:: Multi-step reaction with 20 steps

1.1: sodium tetrahydroborate / ethanol / 2 h / -78 °C / Inert atmosphere

2.1: dichloromethane / 1 h / 20 °C / Inert atmosphere; Molecular sieve

2.2: 39 h / 20 °C / Inert atmosphere

3.1: triethylamine / dichloromethane / 0 - 20 °C / Inert atmosphere

4.1: 2,6-di-tert-butyl-4-methylpyridine; 2,3-dicyano-5,6-dichloro-p-benzoquinone / acetonitrile / 20 °C / Inert atmosphere

5.1: sodium tetrahydroborate / tetrahydrofuran; ethanol / -40 - -30 °C / Inert atmosphere

6.1: sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 13 °C / Inert atmosphere

7.1: lithium borohydride / tetrahydrofuran / Inert atmosphere; Reflux

7.2: 4 h / 20 °C / Inert atmosphere

8.1: lithium borohydride / tetrahydrofuran / 26.5 h / 20 °C / Inert atmosphere; Reflux

8.2: 4 h / 20 °C / Inert atmosphere

9.1: water; acetic acid / tetrahydrofuran / 2 h / 20 °C / Inert atmosphere

10.1: dmap / pyridine; dichloromethane / 24 h / 20 °C / Inert atmosphere

11.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 1 h / 0 °C / Inert atmosphere

12.1: peracetic acid; mercury(II) diacetate; acetic acid / 4 h / 20 °C / Inert atmosphere

13.1: 1H-imidazole / dichloromethane / 4 h / 0 °C / Inert atmosphere

14.1: dmap / pyridine; dichloromethane / 0 - 40 °C / Inert atmosphere

15.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 2 h / 0 °C / Inert atmosphere

16.1: Dess-Martin periodane / dichloromethane / 0 - 20 °C / Inert atmosphere

17.1: Wilkinson's catalyst; triphenylphosphine; isopropyl alcohol / tetrahydrofuran / 16 h / 20 °C / Inert atmosphere

18.1: osmium(VIII) oxide; 4-methylmorpholine N-oxide / water; acetone / 5 h / 20 °C / Inert atmosphere

19.1: di(n-butyl)tin oxide / benzene / 16 h / Reflux; Inert atmosphere

19.2: 0.17 h / 20 °C / Inert atmosphere; Molecular sieve

20.1: triethylamine / benzene / 24 h / 20 °C / Inert atmosphere

With 1H-imidazole; peracetic acid; dmap; sodium tetrahydroborate; Wilkinson's catalyst; osmium(VIII) oxide; lithium borohydride; 2,6-di-tert-butyl-4-methylpyridine; mercury(II) diacetate; tetrabutyl ammonium fluoride; water; di(n-butyl)tin oxide; sodium hydrogencarbonate; Dess-Martin periodane; acetic acid; 4-methylmorpholine N-oxide; triethylamine; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; isopropyl alcohol; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; pyridine; ethanol; dichloromethane; water; acetone; acetonitrile; benzene; 5.1: Luche reduction / 12.1: Tamao oxidation;
DOI:10.1002/asia.200800429