5-Isopropylidene-2-methyl-2-vinyltetrahydrofuran

Base Information

Chemical Name:5-Isopropylidene-2-methyl-2-vinyltetrahydrofuran
CAS No.:67304-14-7
Molecular Formula:C10H16 O
Molecular Weight:152.236
Hs Code.:
European Community (EC) Number:266-636-8
DSSTox Substance ID:DTXSID10986568
Nikkaji Number:J276.757K
Mol file:67304-14-7.mol

Synonyms:67304-14-7;5-Isopropylidene-2-methyl-2-vinyltetrahydrofuran;EINECS 266-636-8;DTXSID10986568;2-ETHENYL-2-METHYL-5-(PROPAN-2-YLIDENE)OXOLANE;2-Ethenyltetrahydro-2-methyl-5-(1-methylethylidene)furan

Suppliers and Price of 5-Isopropylidene-2-methyl-2-vinyltetrahydrofuran

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 6 raw suppliers

Chemical Property of 5-Isopropylidene-2-methyl-2-vinyltetrahydrofuran

Chemical Property:

Vapor Pressure:0.847mmHg at 25°C
Boiling Point:187.9°C at 760 mmHg
Flash Point:59.1°C
PSA：9.23000
Density:0.945g/cm³
LogP:3.03540
XLogP3:2.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:152.120115130
Heavy Atom Count:11
Complexity:199

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=C1CCC(O1)(C)C=C)C

Technology Process of 5-Isopropylidene-2-methyl-2-vinyltetrahydrofuran

There total 5 articles about 5-Isopropylidene-2-methyl-2-vinyltetrahydrofuran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 71328-53-5
5-(1'-bromo-1'-methyl) ethyl-2-methyl-2-vinyltetrahydrofurane

: 67304-14-7
2-methyl-2-vinyl-5-isopropylidenetetrahydrofuran

Guidance literature:: With potassium tert-butylate; In tetrahydrofuran; tert-butyl alcohol; at 50 - 60 ℃; for 1h;
DOI:10.1021/jo00290a018

Reference yield:

: 78-70-6
3,7-dimethylocta-1,6-dien-3-ol

: 67304-14-7
2-methyl-2-vinyl-5-isopropylidenetetrahydrofuran

Guidance literature:: With potassium tert-butylate; Yield given. Multistep reaction;
DOI:10.1016/0040-4020(84)85080-2

Reference yield:

: 118989-24-5
5-ethenyl-5-methyl-2-<1-methyl-1-(phenylseleno)ethyl>tetrahydrofuran

: 67304-14-7
2-methyl-2-vinyl-5-isopropylidenetetrahydrofuran

Guidance literature:: Multi-step reaction with 2 steps

1: 85 percent / hydrogen peroxide / tetrahydrofuran / 1.) 0 -> 25 deg C, 2.) 25 deg C, 24 h

2: RhCl₃ / Ambient temperature

With rhodium(III) chloride; dihydrogen peroxide; In tetrahydrofuran;