Furan, 2-ethenyltetrahydro-2-methyl-5-(1-methylethenyl)-

Base Information

• Chemical Name: Furan, 2-ethenyltetrahydro-2-methyl-5-(1-methylethenyl)-
• CAS No.: 13679-86-2
• Molecular Formula: C10H16 O
• Molecular Weight: 152.236
• Hs Code.: 2932190090
• European Community (EC) Number: 237-184-9
• DSSTox Substance ID: DTXSID20864429
• Nikkaji Number: J277.988I
• Wikidata: Q67879781
• Metabolomics Workbench ID: 47661
• Mol file: 13679-86-2.mol

Synonyms:13679-86-2;2-Isopropenyl-5-methyl-5-vinyltetrahydrofuran;Anhydrolinalool oxide;Furan, 2-ethenyltetrahydro-2-methyl-5-(1-methylethenyl)-;2-ethenyl-2-methyl-5-prop-1-en-2-yloxolane;cis-anhydro linalool oxide;Tetrahydro-5-isopropenyl-2-methyl-2-vinylfuran;Dehydroxylinalool Oxide;5-Isopropenyl-2-methyl-2-vinyltetrahydrofuran;UNII-F2S8JZM40P;2-Ethenyltetrahydro-2-methyl-5-(1-methylethenyl)furan;FEMA No. 3759;FEMA3759;2-Methyl-2-vinyl-5-isopropenyltetrahydrofuran;EINECS 237-184-9;2-Ethenyl-2-methyl-5-(1-methylethenyl)tetrahydrofuran;5-ISOPROPENYL-2-METHYL-2-VINYL TETRAHYDROFURAN;Furan, tetrahydro-5-isopropenyl-2-methyl-2-vinyl-;Lime oxide T;F2S8JZM40P;SCHEMBL872776;DEHYDROXY LINALOOL OXIDE;2-methyl-5-(prop-1-en-2-yl)-2-vinyltetrahydrofuran;FEMA 3759;DTXSID20864429;CHEBI:171918;MFCD00065422;AKOS006283215;5-Isopropenyl-2-methyl-2-vinyl-oxolan;BS-20804;CS-0205438;FT-0636936;I0744;D91198;2-ethenyl-2-methyl-5-(prop-1-en-2-yl)oxolane;Tetrahydro-5-isopropenyl-2-methyl-2-vinyl-Furan;5-Isopropenyl-2-methyl-2-vinyltetrahydrofuran, 9CI;J-006912;Q67879781;2-Ethenyltetrahydro-2-methyl-5-(1-methylethenyl)-Furan;5-Isopropenyl-2-methyl-2-vinyltetrahydrofuran, AldrichCPR;(2R,5S)-2-Methyl-5-(prop-1-en-2-yl)-2-vinyltetrahydrofuran;2-Ethenyltetrahydro-2-methyl-5-(1-methylethenyl)furan, 9CI;tetrahydro - 5 - isopropenyl - 2 - methyl - 2 - vinylfuran

Chemical Property of Furan, 2-ethenyltetrahydro-2-methyl-5-(1-methylethenyl)-

Chemical Property:

• Vapor Pressure: 1.58mmHg at 25°C
• Refractive Index: 1.4500 to 1.4550
• Boiling Point: 174.9°C at 760 mmHg
• Flash Point: 52.1°C
• PSA: 9.23000
• Density: 0.925g/cm³
• LogP: 2.68620
• Storage Temp.: Amber Vial, Refrigerator, Under inert atmosphere
• Solubility.: Chlorofom (Slightly), Methanol (Slightly)
• XLogP3: 2.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 152.120115130
• Heavy Atom Count: 11
• Complexity: 183

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-Ethenyl-2-methyl-5-prop-1-en-2-yloxolane ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 22

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)C1CCC(O1)(C)C=C
• Description: 5-Isopropenyl-2-methyl-2-vinyltetrahydrofuran has a pungent, herbaceous, green, boldo-like camphoraceous, piney, terpene-like, and slightly cineol-like odor.

Technology Process of Furan, 2-ethenyltetrahydro-2-methyl-5-(1-methylethenyl)-

There total 15 articles about Furan, 2-ethenyltetrahydro-2-methyl-5-(1-methylethenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

6-chloro-3,7-dimethylocta-1,7-dien-3-ol (74514-23-1) → 2-methyl-5-(prop-1-en-2-yl)-2-vinyltetrahydrofuran (13679-86-2)

Guidance literature:

With potassium hydroxide; N-benzyl-N,N,N-triethylammonium chloride; In methanol; water; at 25 ℃; for 7h;

DOI:10.1007/BF00953619

Reference yield: 85.0%

5-ethenyl-5-methyl-2-<1-methyl-1-(phenylseleno)ethyl>tetrahydrofuran (118989-24-5) → 2-methyl-5-(prop-1-en-2-yl)-2-vinyltetrahydrofuran (13679-86-2)

Guidance literature:

With dihydrogen peroxide; In tetrahydrofuran; 1.) 0 -> 25 deg C, 2.) 25 deg C, 24 h;

Reference yield: 75.0%

3,7-dimethylocta-1,6-dien-3-ol (78-70-6) → 2-methyl-5-(prop-1-en-2-yl)-2-vinyltetrahydrofuran (13679-86-2) + 6-chloro-3,7-dimethylocta-1,7-dien-3-ol (74514-23-1)

Guidance literature:

With sulfuryl dichloride; sodium carbonate; In dichloromethane; at 0 ℃;

DOI:10.1016/S0040-4039(00)76192-2

upstream raw materials:

6,7-epoxymyrcene

methanol

3,7-dimethylocta-1,6-dien-3-ol

6-chloro-3,7-dimethylocta-1,7-dien-3-ol

Downstream raw materials:

2,2,5-trimethylcyclohept-4-en-1-one

2-methyl-2-vinyl-5-isopropylidenetetrahydrofuran