benzyl bis(3,4-dihydroxybutyl)carbamate

Base Information

Chemical Name:benzyl bis(3,4-dihydroxybutyl)carbamate
CAS No.:1269788-39-7
Molecular Formula:C₁₆H₂₅NO₆
Molecular Weight:327.378
Hs Code.:

Synonyms:benzyl bis(3,4-dihydroxybutyl)carbamate

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Chemical Property of benzyl bis(3,4-dihydroxybutyl)carbamate

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Technology Process of benzyl bis(3,4-dihydroxybutyl)carbamate

There total 1 articles about benzyl bis(3,4-dihydroxybutyl)carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1226779-54-9
benzyl dibut-3-enylcarbamate

: 1269788-39-7
benzyl bis(3,4-dihydroxybutyl)carbamate

Guidance literature:: With osmium(VIII) oxide; potassium carbonate; potassium hexacyanoferrate(III); In water; tert-butyl alcohol; at 20 ℃; for 36h; Inert atmosphere;
DOI:10.1016/j.tetlet.2010.12.066

Reference yield: 100.0%

: 1269788-39-7
benzyl bis(3,4-dihydroxybutyl)carbamate

: 1269788-40-0
benzyl bis(2-formylethyl)carbamate

Guidance literature:: With sodium periodate; silica gel; In dichloromethane; water; at 20 ℃; for 1h; Inert atmosphere;
DOI:10.1016/j.tetlet.2010.12.066

Reference yield:

: 1269788-39-7
benzyl bis(3,4-dihydroxybutyl)carbamate

: 56-54-2,130-95-0,572-59-8,572-60-1,42151-59-7,47342-58-5,72402-50-7,72402-51-8,72402-52-9,72402-53-0,101143-86-6,101143-87-7,101143-88-8,146925-10-2
quinindine

Guidance literature:: Multi-step reaction with 18 steps

1.1: sodium periodate; silica gel / dichloromethane; water / 1 h / 20 °C / Inert atmosphere

2.1: (S)-2-{bis[3,5-bis(trifluoromethyl)phenyl][(trimethylsilanyl)oxy]methyl}pyrrolidine / dichloromethane / 36 h / 4 °C

2.2: -5 °C

3.1: n-butyllithium; diisopropylamine / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere

3.2: 1.5 h / -78 °C / Inert atmosphere

4.1: 20 % Pd(OH)2/C; hydrogen / ethyl acetate / 6 h / 20 °C / Inert atmosphere

5.1: pyridine; dmap / 0.75 h / 0 - 20 °C / Inert atmosphere

6.1: n-butyllithium; diisopropylamine / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere

6.2: 12 h / -65 °C / Inert atmosphere

7.1: sodium tetrahydroborate / methanol / 2 h / 20 °C / Cooling with ice; Inert atmosphere

8.1: pyridine / 1.5 h / 0 - 20 °C / Inert atmosphere

9.1: potassium tert-butylate / tetrahydrofuran / 1.5 h / 0 °C / Inert atmosphere

10.1: methanesulfonamide; hydroquinidein 1,4-phthalazinediyl diether / water; tert-butyl alcohol / 72 h / 4 °C / Inert atmosphere

11.1: Trimethyl orthoacetate; pyridinium p-toluenesulfonate / dichloromethane / 5 h / 20 °C / Inert atmosphere

11.2: 3 h / 20 °C / Inert atmosphere

11.3: 2 h / 20 °C / Inert atmosphere

12.1: diisobutylaluminium hydride / hexane; toluene / 0.33 h / -78 °C / Inert atmosphere

13.1: N,N-dimethyl-formamide / 4 h / Reflux; Inert atmosphere

14.1: dmap; triethylamine / tetrahydrofuran / 3 h / 0 °C / Inert atmosphere

15.1: hydrogenchloride; methanol / 5 h / 20 °C / Inert atmosphere

16.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / -78 °C / Inert atmosphere

16.2: -78 - 0 °C / Inert atmosphere

17.1: potassium tert-butylate / tetrahydrofuran / 0.5 h / 0 °C / Inert atmosphere

17.2: 0.5 h / 0 °C

18.1: methanol; potassium carbonate / 1.5 h / 20 °C / Inert atmosphere

With pyridine; (S)-2-{bis[3,5-bis(trifluoromethyl)phenyl][(trimethylsilanyl)oxy]methyl}pyrrolidine; hydrogenchloride; methanol; Trimethyl orthoacetate; dmap; sodium tetrahydroborate; sodium periodate; n-butyllithium; oxalyl dichloride; methanesulfonamide; 20 % Pd(OH)2/C; potassium tert-butylate; hydrogen; pyridinium p-toluenesulfonate; silica gel; diisobutylaluminium hydride; potassium carbonate; dimethyl sulfoxide; hydroquinidein 1,4-phthalazinediyl diether; triethylamine; diisopropylamine; N,N-dimethyl-formamide; In tetrahydrofuran; methanol; hexane; dichloromethane; water; ethyl acetate; toluene; tert-butyl alcohol; 3.1: Peterson olefination / 3.2: Peterson olefination / 16.1: Swern oxidation / 16.2: Swern oxidation / 17.1: Wittig reaction / 17.2: Wittig reaction;
DOI:10.1016/j.tetlet.2010.12.066