(2E,4E,6E,8E)-4-Butylaminomethyl-7-methyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,4,6,8-tetraenoic acid ethyl ester

Base Information

Chemical Name:(2E,4E,6E,8E)-4-Butylaminomethyl-7-methyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,4,6,8-tetraenoic acid ethyl ester
CAS No.:87927-40-0
Molecular Formula:C₂₆H₄₁NO₂
Molecular Weight:399.617
Hs Code.:

Synonyms:(2E,4E,6E,8E)-4-Butylaminomethyl-7-methyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,4,6,8-tetraenoic acid ethyl ester

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Chemical Property of (2E,4E,6E,8E)-4-Butylaminomethyl-7-methyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,4,6,8-tetraenoic acid ethyl ester

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Technology Process of (2E,4E,6E,8E)-4-Butylaminomethyl-7-methyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,4,6,8-tetraenoic acid ethyl ester

There total 9 articles about (2E,4E,6E,8E)-4-Butylaminomethyl-7-methyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,4,6,8-tetraenoic acid ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 99213-68-0
(2E,4E,6E,8E)-4-[(E)-Butyliminomethyl]-7-methyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,4,6,8-tetraenoic acid ethyl ester

: 87927-40-0
(2E,4E,6E,8E)-4-Butylaminomethyl-7-methyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,4,6,8-tetraenoic acid ethyl ester

Guidance literature:: With sodium tetrahydroborate; In ethanol; at 25 ℃; for 3h; Yield given;
DOI:10.1021/ja00311a050

Reference yield:

: 87927-38-6
(2E,4E,6E,8E)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-7-methyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,4,6,8-tetraenoic acid ethyl ester

: 87927-40-0
(2E,4E,6E,8E)-4-Butylaminomethyl-7-methyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,4,6,8-tetraenoic acid ethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 1) Bu₄NF, 2) MnO₂ / 1) THF

2: NaBH₄

With manganese(IV) oxide; sodium tetrahydroborate; tetrabutyl ammonium fluoride;
DOI:10.1039/c39830000077

Reference yield:

: 3917-41-7
(2E,4E)-3-methyl-5-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2,4-pentadienal

: 87927-40-0
(2E,4E,6E,8E)-4-Butylaminomethyl-7-methyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,4,6,8-tetraenoic acid ethyl ester

Guidance literature:: Multi-step reaction with 8 steps

1: 85 percent / NaH / tetrahydrofuran; hexamethylphosphoric acid triamide / 1 h / Ambient temperature

2: 1.) 1 M diisobutylaluminum hydride (DIBAL), ethyl acetate; 2.) water / 1.) hexane, -78 deg C, 30 min; 2.) rt., 3 h

3: 88 percent / imidazole / dimethylformamide / 2 h / 25 °C

4: 67 percent / NaH / tetrahydrofuran / 1 h / Ambient temperature

5: 1 M tetrabutylammonium fluoride / tetrahydrofuran / 0.5 h / 25 °C

6: 84 percent / MnO₂ / CH₂Cl₂ / 2 h / 25 °C

7: ethanol / 3 h / 0 °C

8: NaBH₄ / ethanol / 3 h / 25 °C

With 1H-imidazole; manganese(IV) oxide; sodium tetrahydroborate; tetrabutyl ammonium fluoride; water; sodium hydride; diisobutylaluminium hydride; ethyl acetate; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; ethanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja00311a050